{"title":"Room-Temperature Synthesis, Characterization, and Protonation of Two Zinc Phthalocyanines With Unsaturated Groups","authors":"Mengyao Han, Zhiqiang Shang, Fangdi Cong, Dajuan Zhang, Zhaowang Shen, Wei Yang, Lu Jiang, Yingchao Wang, Liwang Zhang, Zhongli Wang, Bingqian Liu, Daying Liu","doi":"10.1002/jhet.4937","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>To explore the room-temperature synthesis of metal phthalocyanines with unsaturated substituents, two zinc phthalocyanines with unsaturated alkoxy groups were synthesized in a reaction system composed of 4-citronellol-oxy-phthalonitrile or 4-geraniol-oxy-phthalonitrile, Zn(OAc)<sub>2</sub>⋅2H<sub>2</sub>O, DBU, and ethanol, at room temperature. The synthetic reactions lasted for 7 days and the yields of two phthalocyanine derivatives reached 21% and 18%, respectively, and they are inclined to protonation in a non-coordinated organic solvent, for example, CHCl<sub>3</sub>. By the way, the phthalocyanine compounds with other metals, such as Cu, Ni, and Co, cannot be prepared. This work will provide preference for improving the synthetic method in the future, so as to synthesize many new phthalocyanine compounds in general laboratories.</p>\n </div>","PeriodicalId":194,"journal":{"name":"Journal of Heterocyclic Chemistry","volume":"62 2","pages":"202-208"},"PeriodicalIF":2.0000,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Heterocyclic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/jhet.4937","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
To explore the room-temperature synthesis of metal phthalocyanines with unsaturated substituents, two zinc phthalocyanines with unsaturated alkoxy groups were synthesized in a reaction system composed of 4-citronellol-oxy-phthalonitrile or 4-geraniol-oxy-phthalonitrile, Zn(OAc)2⋅2H2O, DBU, and ethanol, at room temperature. The synthetic reactions lasted for 7 days and the yields of two phthalocyanine derivatives reached 21% and 18%, respectively, and they are inclined to protonation in a non-coordinated organic solvent, for example, CHCl3. By the way, the phthalocyanine compounds with other metals, such as Cu, Ni, and Co, cannot be prepared. This work will provide preference for improving the synthetic method in the future, so as to synthesize many new phthalocyanine compounds in general laboratories.
期刊介绍：
The Journal of Heterocyclic Chemistry is interested in publishing research on all aspects of heterocyclic chemistry, especially development and application of efficient synthetic methodologies and strategies for the synthesis of various heterocyclic compounds. In addition, Journal of Heterocyclic Chemistry promotes research in other areas that contribute to heterocyclic synthesis/application, such as synthesis design, reaction techniques, flow chemistry and continuous processing, multiphase catalysis, green chemistry, catalyst immobilization and recycling.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
