Iron Nanoparticle-Catalyzed Enantioselective Electro-Organic Carboxylation of Styrenes with CO2 Using Graphene Oxide Modified with PyrCO-cyclo@Fe in the Presence of Deep Eutectic Electrolyte and Solvent

IF 2.1 4区化学 Q3 CHEMISTRY, PHYSICAL

Catalysis Surveys from Asia Pub Date : 2024-11-08 DOI:10.1007/s10563-024-09439-w

Amer Alhaj Zen, Majid S. Jabir, Zaman Abdalhussein Ibadi Alaridhee, Rafid Kamal Jameel, Morug Salih Mahdi, Aseel Salah Mansoor, Usama Kadem Radi, Ameer Hassan Idan, Hala Bahair, Elyor Berdimurodov, Hasan Majdi, Abdulrahman A. Almehizia

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Abstract

This study explores the use of graphene oxide (GO) modified with PyrCO-cyclo@Fe as an efficient and selective catalyst. The modification of GO with PyrCO-cyclo@Fe provides a robust platform for the synthesis of (S)-2-phenylpropanoic acid derivatives 4(a–l), facilitated by the presence of choline chloride ethylene glycol (ChCl/EGC) as the electrolyte in good to excellent yields (89–97%). The experimental results demonstrate that this catalytic system not only enhances the enantioselectivity of the carboxylation process but also improves the overall yield and efficiency. This method presents a promising approach for the production of valuable enantioenriched carboxylic acids, contributing to the development of green and sustainable catalytic processes in organic synthesis. The synthesized GO-PyrCO-cyclo@Fe electrode was examined utilizing various analytical methods, including FT-IR, CV, SEM, EDS, BET, TGA, and XPS The synthesized (S)-2-phenylpropanoic acid derivatives 4(a–l) were identified and characterized through melting point determination, FT-IR, ¹HNMR, and CHN analyses.

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来源期刊

Catalysis Surveys from Asia 化学-物理化学

CiteScore

4.80

自引率

0.00%

发文量

审稿时长

>12 weeks

期刊介绍： Early dissemination of important findings from Asia which may lead to new concepts in catalyst design is the main aim of this journal. Rapid, invited, short reviews and perspectives from academia and industry will constitute the major part of Catalysis Surveys from Asia . Surveys of recent progress and activities in catalytic science and technology and related areas in Asia will be covered regularly as well. We would appreciate critical comments from colleagues throughout the world about articles in Catalysis Surveys from Asia . If requested and thought appropriate, the comments will be included in the journal. We will be very happy if this journal stimulates global communication between scientists and engineers in the world of catalysis.