Biochar Prepared from Sugarcane Bagasse for the Clarification of Brown Sugar Solutions

IF 1.8 3区 农林科学 Q2 AGRONOMY
Jaqueline do Carmo Lima Carvalho, Nathalia Eugênia Silva, Marina Costa Patrocínio, Osania Emerenciano Ferreira, Robson Pereira de Lima, Magno André de Oliveira, Marcello Rosa Dumont, Augusto César da Silva Bezerra, Alan Rodrigues Teixeira Machado
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Abstract

The industry is actively seeking innovative technologies to eliminate color and other impurities in the production of refined sugar. This study evaluated the potential of biochar samples for sugar clarification using a brown sugar solution as a model. To this end, samples of biochar were produced from sugarcane bagasse under different pyrolysis temperatures (300 °C, 600 °C, 800 °C, and 1000 °C). In the clarification test, the samples were exposed to brown sugar solution (10 g.L−1) for 1 h, and color reduction was monitored using UV‒Vis spectroscopy. As expected, varying the pyrolysis temperature caused changes in the physicochemical properties of the biochar. With increasing temperature, the carbon content, fixed carbon content, ash content, specific surface area, pH, and thermal stability increased, whereas the volatile material content, oxygen content, and gravimetric yield decreased. The pyrolysis temperature also influenced the color reduction ability of the brown sugar solution. When the pyrolysis temperature increased, the percentage color reduction also increased. Thus, the sample pyrolyzed at the highest temperature investigated (1000 °C) presented the greatest clarifying potential, reducing the color of a brown sugar solution (10 g.L−1) by 87%. Furthermore, the UV‒Vis spectrum indicated the removal of dyes, including caramels, melanoidins, and hexose alkaline degradation products, from the brown sugar solution. Therefore, sugarcane biochar has the potential for sustainable application in sugar clarification processes.

用甘蔗渣制备生物炭澄清红糖溶液
该行业正在积极寻求创新技术,以消除精制糖生产中的颜色和其他杂质。本研究以红糖溶液为模型,评估了生物炭样品用于糖澄清的潜力。为此,以甘蔗渣为原料,在不同热解温度(300℃、600℃、800℃、1000℃)下制备生物炭样品。在澄清试验中,将样品暴露于红糖溶液(10 g.L−1)中1小时,并使用紫外可见光谱监测颜色还原。正如预期的那样,改变热解温度会导致生物炭的理化性质发生变化。随着温度的升高,其含碳量、固定碳含量、灰分含量、比表面积、pH值和热稳定性增加,挥发性物质含量、氧含量和重收率降低。热解温度对红糖溶液的还色能力也有影响。随着热解温度的升高,颜色还原率也随之增加。因此,在最高温度(1000°C)下热解的样品具有最大的澄清潜力,使红糖溶液(10 g.L−1)的颜色降低87%。此外,紫外可见光谱表明,从红糖溶液中去除染料,包括焦糖、类黑素和己糖碱性降解产物。因此,甘蔗生物炭在糖澄清过程中具有可持续应用的潜力。
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来源期刊
Sugar Tech
Sugar Tech AGRONOMY-
CiteScore
3.90
自引率
21.10%
发文量
145
期刊介绍: The journal Sugar Tech is planned with every aim and objectives to provide a high-profile and updated research publications, comments and reviews on the most innovative, original and rigorous development in agriculture technologies for better crop improvement and production of sugar crops (sugarcane, sugar beet, sweet sorghum, Stevia, palm sugar, etc), sugar processing, bioethanol production, bioenergy, value addition and by-products. Inter-disciplinary studies of fundamental problems on the subjects are also given high priority. Thus, in addition to its full length and short papers on original research, the journal also covers regular feature articles, reviews, comments, scientific correspondence, etc.
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