Synthesis, characterization and antimicrobial activity of Ferrocene based bimetallic Zn (II) complexes with mixed-ligands containing 2, 2-bipyridyl and 1, 10-phenanthroline

IF 2.1 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Organometallic Chemistry Pub Date : 2024-12-26 DOI:10.1016/j.jorganchem.2024.123490

Gul Wali Khan , Abid Ali , Muhammad Adeel Asghar , Warda Mansur , Saneea Atta ul Haq , Munawar Iqbal , Samiah H. Al-Mijalli , Wissem Mnif

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引用次数: 0

Abstract

Three novel ferrocene-based organometallic complexes of zinc, containing either homoleptic or heteroleptic (mixed-ligand) structures [Zn (FcBz)₂ (H₂O)₂] (1), [Zn (FcBz)₂ Bipy] (2), [Zn (FcBz)₂ Phen] (3), which FcBz = 4-ferrocenyl benzoate, Phen = 1, 10-phenanthroline, Bipy = 2, 2-bipyridyl, were chemically synthesized and well characterized by ¹³C NMR, ¹H NMR, FT-IR, elemental analysis and thermal gravimetric analysis (TGA). The synthesized complexes incorporate ligands that exhibit bidentate chelation, resulting in hexacoordinate geometry. The complexes were exposed to antibacterial testing against pathogenic Gram-negative and Gram-positive bacteria. Antimicrobial research revealed that heteroleptic complexes outperformed homoleptic ones. The [Zn (FcBz)₂Phen] complex exhibited the highest efficacy, making it a viable organometallic contender for antibacterial applications.

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来源期刊

Journal of Organometallic Chemistry 化学-无机化学与核化学

CiteScore

4.40

自引率

8.70%

发文量

221

审稿时长

36 days

期刊介绍： The Journal of Organometallic Chemistry targets original papers dealing with theoretical aspects, structural chemistry, synthesis, physical and chemical properties (including reaction mechanisms), and practical applications of organometallic compounds. Organometallic compounds are defined as compounds that contain metal - carbon bonds. The term metal includes all alkali and alkaline earth metals, all transition metals and the lanthanides and actinides in the Periodic Table. Metalloids including the elements in Group 13 and the heavier members of the Groups 14 - 16 are also included. The term chemistry includes syntheses, characterizations and reaction chemistry of all such compounds. Research reports based on use of organometallic complexes in bioorganometallic chemistry, medicine, material sciences, homogeneous catalysis and energy conversion are also welcome. The scope of the journal has been enlarged to encompass important research on organometallic complexes in bioorganometallic chemistry and material sciences, and of heavier main group elements in organometallic chemistry. The journal also publishes review articles, short communications and notes.