Angus G. Campbell , Ian Cartwright , John A. Webb , Dioni I. Cendón , Matthew J. Currell
{"title":"Using geochemical and geophysical data to characterise inter-aquifer connectivity and impacts on shallow aquifers and groundwater dependent ecosystems","authors":"Angus G. Campbell , Ian Cartwright , John A. Webb , Dioni I. Cendón , Matthew J. Currell","doi":"10.1016/j.apgeochem.2024.106217","DOIUrl":null,"url":null,"abstract":"<div><div>Understanding inter-aquifer connectivity within sedimentary basins is crucial for determining how groundwater extraction will impact groundwater resources and groundwater dependent ecosystems (GDEs). Geophysical, geochemical and radioisotope data were combined to understand whether dewatering for open-cut coal mining in Australia's Galilee Basin will be likely to impact groundwater levels in overlying aquifers sustaining the ecologically significant Doongmabulla Springs Complex and Carmichael River. Groundwater salinities (<300 mg/L), measurable <sup>3</sup>H (0.43 TU), and activities of radiocarbon a<sup>14</sup>C (14.1 – 95.3 pMC) and chlorine-36 R<sup>36</sup>Cl (78.1 × 10<sup>−15</sup> – 161 × 10<sup>−15</sup>) imply that preferential pathways for groundwater flow and recharge occur through the weathered sub-crop of the Galilee Basin sediments. These high permeability zones occur consistently within 5 km of the mine (and further to the south), where strong overlap in major ion and radioisotope compositions indicates significant groundwater connectivity between aquifers. Elevated groundwater HCO<sub>3</sub> and F concentrations and heavy fraction hydrocarbons (>100 μg/L C<sub>10</sub>–C<sub>40</sub>) also imply deep groundwater in the coal measures discharges into overlying non-coal bearing aquifers, most likely via faults. Since coal mine dewatering commenced, drawdown has spread preferentially southward from the mine, driven by geological heterogeneity including into aquifers that are not targeted by mining. Drawdown is also migrating gradually into shallow aquifers west of the mine, towards GDEs along the Carmichael River valley. Numerical modelling of the mine's groundwater impacts, which was the basis of the mine's approval, did not anticipate this level of drawdown in shallow aquifers at this stage of mining. Mining impacts on shallow groundwater resources and GDEs, including the Doongmabulla springs and the Carmichael River, may have thus been underestimated and require re-evaluation. This study highlights that multiple lines of evidence must be assessed to carefully develop conceptual and numerical models, and to protect groundwater and GDEs.</div></div>","PeriodicalId":8064,"journal":{"name":"Applied Geochemistry","volume":"178 ","pages":"Article 106217"},"PeriodicalIF":3.1000,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Geochemistry","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0883292724003226","RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
引用次数: 0
Abstract
Understanding inter-aquifer connectivity within sedimentary basins is crucial for determining how groundwater extraction will impact groundwater resources and groundwater dependent ecosystems (GDEs). Geophysical, geochemical and radioisotope data were combined to understand whether dewatering for open-cut coal mining in Australia's Galilee Basin will be likely to impact groundwater levels in overlying aquifers sustaining the ecologically significant Doongmabulla Springs Complex and Carmichael River. Groundwater salinities (<300 mg/L), measurable 3H (0.43 TU), and activities of radiocarbon a14C (14.1 – 95.3 pMC) and chlorine-36 R36Cl (78.1 × 10−15 – 161 × 10−15) imply that preferential pathways for groundwater flow and recharge occur through the weathered sub-crop of the Galilee Basin sediments. These high permeability zones occur consistently within 5 km of the mine (and further to the south), where strong overlap in major ion and radioisotope compositions indicates significant groundwater connectivity between aquifers. Elevated groundwater HCO3 and F concentrations and heavy fraction hydrocarbons (>100 μg/L C10–C40) also imply deep groundwater in the coal measures discharges into overlying non-coal bearing aquifers, most likely via faults. Since coal mine dewatering commenced, drawdown has spread preferentially southward from the mine, driven by geological heterogeneity including into aquifers that are not targeted by mining. Drawdown is also migrating gradually into shallow aquifers west of the mine, towards GDEs along the Carmichael River valley. Numerical modelling of the mine's groundwater impacts, which was the basis of the mine's approval, did not anticipate this level of drawdown in shallow aquifers at this stage of mining. Mining impacts on shallow groundwater resources and GDEs, including the Doongmabulla springs and the Carmichael River, may have thus been underestimated and require re-evaluation. This study highlights that multiple lines of evidence must be assessed to carefully develop conceptual and numerical models, and to protect groundwater and GDEs.
期刊介绍:
Applied Geochemistry is an international journal devoted to publication of original research papers, rapid research communications and selected review papers in geochemistry and urban geochemistry which have some practical application to an aspect of human endeavour, such as the preservation of the environment, health, waste disposal and the search for resources. Papers on applications of inorganic, organic and isotope geochemistry and geochemical processes are therefore welcome provided they meet the main criterion. Spatial and temporal monitoring case studies are only of interest to our international readership if they present new ideas of broad application.
Topics covered include: (1) Environmental geochemistry (including natural and anthropogenic aspects, and protection and remediation strategies); (2) Hydrogeochemistry (surface and groundwater); (3) Medical (urban) geochemistry; (4) The search for energy resources (in particular unconventional oil and gas or emerging metal resources); (5) Energy exploitation (in particular geothermal energy and CCS); (6) Upgrading of energy and mineral resources where there is a direct geochemical application; and (7) Waste disposal, including nuclear waste disposal.