Progress and outlook of ferroelectric/non-ferroelectric polar glass-ceramics for multi-catalytic applications

IF 10.5 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Progress in Solid State Chemistry Pub Date : 2024-11-12 DOI:10.1016/j.progsolidstchem.2024.100497

Chirag Porwal , Gurpreet Singh , Moolchand Sharma , Vishal Singh Chauhan , Rahul Vaish

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Abstract

Glass-ceramics have been long recognized for their capability to offer shared characteristics of both glassy as well as crystalline phases. By controlling volume fraction of crystalline phase dispersed in glassy matrix, the properties of glass-ceramics can be tuned for variety of applications such as dental implants, heat-resistant cooking ware, missiles nozzle cones, etc. A specific family of glass-ceramics that consists of ferroelectric/non-ferroelectric polar crystallites offers second-harmonic generation, pyroelectric, piezoelectric, and ferroelectric properties for actuators, sensors, non-linear optical devices, and lasers applications, that were traditionally not possible in glassy materials. Fabrication, crystallization behavior, and electrical properties of such glass-ceramics have been extensively studied in the last decade and widely reviewed in multiple documents in the literature. Recently, the presence of ferroelectric/non-ferroelectric polar crystallites in glasses unveils the new environmental applications of glass-ceramics using photocatalysis, piezocatalysis, and tribocatalysis processes stimulated by light, mechanical, and frictional energy, respectively. Ferroelectric/non-ferroelectric polar glass-ceramics for multi-catalysis is relatively a new and emerging area, that have potential to provide solution for real-environmental problems such as water-pollution. Thus, this review provides a comprehensive overview of multi-catalytic nature of ferroelectric/non-ferroelectric polar glass-ceramics. It discusses the underlying catalytic mechanisms and unveils the performance of these glass-ceramics in environmental applications. It highlights the advantages and challenges of ferroelectric/non-ferroelectric polar glass-ceramics as photo/piezo/tribocatalysts. This review will motivate glass researchers to work in the area of environmental applications of glass-ceramics using catalytic processes.

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多催化铁电/非铁电极性微晶玻璃的研究进展与展望

玻璃陶瓷长期以来一直被认为具有玻璃相和结晶相的共同特性。通过控制分散在玻璃基体中的晶相的体积分数，可以调整微晶玻璃的性能，用于各种应用，如牙科植入物、耐热炊具、导弹喷嘴锥等。由铁电/非铁电极性晶体组成的特定玻璃陶瓷家族为致动器、传感器、非线性光学器件和激光应用提供了二次谐波产生、热释电、压电和铁电特性，这些特性传统上在玻璃材料中是不可能的。近十年来，人们对这种微晶玻璃的制备、结晶行为和电学性能进行了广泛的研究，并在多篇文献中进行了广泛的综述。最近，铁电/非铁电极性晶体在玻璃中的存在揭示了玻璃陶瓷的新环境应用，分别使用光催化、压电催化和摩擦催化过程，分别受到光、机械和摩擦能的刺激。用于多重催化的铁电/非铁电极性微晶玻璃是一个相对较新的新兴领域，具有解决水污染等实际环境问题的潜力。因此，本文综述了铁电/非铁电极性微晶玻璃的多催化性质。讨论了潜在的催化机制，并揭示了这些微晶玻璃在环境应用中的性能。强调了铁电/非铁电极性微晶玻璃作为光/压电/摩擦催化剂的优势和挑战。本文综述将激励玻璃研究人员在催化工艺的环境应用领域开展工作。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Progress in Solid State Chemistry 化学-无机化学与核化学

CiteScore

14.10

自引率

3.30%

发文量

期刊介绍： Progress in Solid State Chemistry offers critical reviews and specialized articles written by leading experts in the field, providing a comprehensive view of solid-state chemistry. It addresses the challenge of dispersed literature by offering up-to-date assessments of research progress and recent developments. Emphasis is placed on the relationship between physical properties and structural chemistry, particularly imperfections like vacancies and dislocations. The reviews published in Progress in Solid State Chemistry emphasize critical evaluation of the field, along with indications of current problems and future directions. Papers are not intended to be bibliographic in nature but rather to inform a broad range of readers in an inherently multidisciplinary field by providing expert treatises oriented both towards specialists in different areas of the solid state and towards nonspecialists. The authorship is international, and the subject matter will be of interest to chemists, materials scientists, physicists, metallurgists, crystallographers, ceramists, and engineers interested in the solid state.