Effect of Cu–Sn–Ti Solder Alloy on Morphology, Bonding Interface, and Mechanical Properties of Brazed Diamond Grits

IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY
Jun Zhang, Kai Li, Zhe Zhang, Jiarong Chen, Peicheng Mo, Xiaoyi Pan, Qiaofan Hu, Chao Chen
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Abstract

The present study focused on characterizing Cu70–Sn20–Ti10 solder alloy powder used for brazing diamond grits in a vacuum at 960°C for 20 min. The study covered the macroscopic and microscopic morphology of Cu–Sn–Ti/diamond, the products and thickness of the interfacial reaction layer, the surface morphology of diamond grits, and the phase and morphology of surface attachments after reaction. Additionally, the effects of graphitization and compressive strength of the diamond after the reaction were also studied. The study’s results revealed that the solder alloy could climb up to the diamond grits effectively and exhibited excellent wettability. Microscopically, a TiC reaction layer was observed at the interface between them, and the thickness of the reaction layer was about 1.92 μm, leading to the realization of a chemical metallurgical combination. After brazing, the uncovered surface of diamond grits appeared smooth and did not show graphitization, except for slight graphitization in a few corrosion pits. Moreover, no significant change was observed in the compressive strength of the diamond before and after brazing.

Abstract Image

Cu-Sn-Ti钎料合金对钎焊金刚石磨粒形貌、结合界面及力学性能的影响
本研究主要对用于金刚石磨粒真空钎焊的Cu70-Sn20-Ti10焊料合金粉末进行了表征。研究内容包括Cu-Sn-Ti /金刚石的宏观和微观形貌、界面反应层的产物和厚度、金刚石磨粒的表面形貌以及反应后表面附着物的物相和形貌。此外,还研究了反应后金刚石的石墨化和抗压强度的影响。研究结果表明,钎料合金可以有效地爬上金刚石磨粒,并表现出良好的润湿性。微观上,在界面处形成TiC反应层,反应层厚度约为1.92 μm,实现了化学冶金结合。钎焊后,未覆盖的金刚石砂表面光滑,除少数腐蚀坑有轻微的石墨化外,未出现石墨化。此外,在钎焊前后,金刚石的抗压强度没有明显变化。
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来源期刊
Journal of Superhard Materials
Journal of Superhard Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
1.80
自引率
66.70%
发文量
26
审稿时长
2 months
期刊介绍: Journal of Superhard Materials presents up-to-date results of basic and applied research on production, properties, and applications of superhard materials and related tools. It publishes the results of fundamental research on physicochemical processes of forming and growth of single-crystal, polycrystalline, and dispersed materials, diamond and diamond-like films; developments of methods for spontaneous and controlled synthesis of superhard materials and methods for static, explosive and epitaxial synthesis. The focus of the journal is large single crystals of synthetic diamonds; elite grinding powders and micron powders of synthetic diamonds and cubic boron nitride; polycrystalline and composite superhard materials based on diamond and cubic boron nitride; diamond and carbide tools for highly efficient metal-working, boring, stone-working, coal mining and geological exploration; articles of ceramic; polishing pastes for high-precision optics; precision lathes for diamond turning; technologies of precise machining of metals, glass, and ceramics. The journal covers all fundamental and technological aspects of synthesis, characterization, properties, devices and applications of these materials. The journal welcomes manuscripts from all countries in the English language.
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