Selective separation of Li, Ni, Co and Mn from model spent Li ion battery cathode materials by dry processing using the combination of chlorination and oxidation†

IF 3.4 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Yuuki Mochizuki and Naoto Tsubouchi
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引用次数: 0

Abstract

The volatilization of Li, Ni, Co, and Mn during chlorination treatment of LNO, LCO, and LMO (model materials for used LIB cathode materials) was investigated with the aim of developing technology for selectively separating and recovering valuable elements by dry methods from used LIB cathode materials. Based on the characterization results for each species, oxidation treatment was performed on LNO, LCO, and LMO after chlorination, and the selective separation of Li from Ni, Co, and Mn was investigated. Volatilization of Li, Ni, Co, and Mn from LNO, LCO, and LMO occurred at over 700 °C during chlorination, and it was difficult to perform selective volatilization separation of the LIB constituent elements. It was found that when LNO, LCO, and LMO were treated by chlorination at up to 600 °C and then heated in air up to 1300 °C, Li could be selectively separated from Ni, Co, and Mn.

Abstract Image

用氯化氧化联合干法从废旧锂离子电池正极材料中选择性分离出Li、Ni、Co和Mn
研究了氯化处理LNO、LCO和LMO(废旧锂电池正极材料的模型材料)过程中Li、Ni、Co和Mn的挥发情况,旨在开发干法从废旧锂电池正极材料中选择性分离和回收有价元素的技术。根据各物种的表征结果,对氯化后的LNO、LCO和LMO进行氧化处理,并对Li与Ni、Co、Mn的选择性分离进行了研究。氯化过程中LNO、LCO和LMO中的Li、Ni、Co和Mn在700℃以上发生挥发,LIB组成元素难以进行选择性挥发分离。结果表明,LNO、LCO和LMO在600℃下进行氯化处理,然后在空气中加热到1300℃,Li可以选择性地从Ni、Co和Mn中分离出来。
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来源期刊
Reaction Chemistry & Engineering
Reaction Chemistry & Engineering Chemistry-Chemistry (miscellaneous)
CiteScore
6.60
自引率
7.70%
发文量
227
期刊介绍: Reaction Chemistry & Engineering is a new journal reporting cutting edge research into all aspects of making molecules for the benefit of fundamental research, applied processes and wider society. From fundamental, molecular-level chemistry to large scale chemical production, Reaction Chemistry & Engineering brings together communities of chemists and chemical engineers working to ensure the crucial role of reaction chemistry in today’s world.
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