Recent progress of microstructure-regulated g-C3N4 in photocatalytic NO conversion: The pivotal roles of adsorption/activation sites

IF 10.8 2区 化学 Q1 CHEMISTRY, PHYSICAL
Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang
{"title":"Recent progress of microstructure-regulated g-C3N4 in photocatalytic NO conversion: The pivotal roles of adsorption/activation sites","authors":"Hui Wang ,&nbsp;Abdelkader Labidi ,&nbsp;Menghan Ren ,&nbsp;Feroz Shaik ,&nbsp;Chuanyi Wang","doi":"10.1016/j.actphy.2024.100039","DOIUrl":null,"url":null,"abstract":"<div><div>Photocatalytic nitric oxide (NO) conversion technology has the characteristics of high efficiency, economy, and environment friendly to remove NO using g-C<sub>3</sub>N<sub>4</sub>. Introducing new adsorption sites on the surface of g-C<sub>3</sub>N<sub>4</sub> through microstructure control can alter the structure-activity relationship between g-C<sub>3</sub>N<sub>4</sub> and gas molecules, thereby improving photocatalytic NO conversion activity and inhibiting NO<sub>2</sub> generation. However, few review articles have focused on the microscopic effects of microstructural changes in g-C<sub>3</sub>N<sub>4</sub> based materials on the adsorption and activation of NO and O<sub>2</sub>. This has important guiding significance for material design work in the field of NO conversion and strategies to fundamentally improve NO conversion activity and selectivity. Therefore, our work systematically summarizes the strategy of introducing adsorption and activation sites through microstructure control, and emphasizes the role of these sites in the photocatalytic NO conversion process. The aim is to clarify the influence of adsorption and activation sites on adsorption behavior and the correlation between these sites and reaction paths. Finally, the development trend and future prospects of increasing the level of g-C<sub>3</sub>N<sub>4</sub> adsorption and activation in the field of photocatalytic NO conversion are introduced, which is expected to provide an important reference for the development and practical application of g-C<sub>3</sub>N<sub>4</sub>-based photocatalytic materials.</div></div>","PeriodicalId":6964,"journal":{"name":"物理化学学报","volume":"41 5","pages":"Article 100039"},"PeriodicalIF":10.8000,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"物理化学学报","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1000681824000766","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

Abstract

Photocatalytic nitric oxide (NO) conversion technology has the characteristics of high efficiency, economy, and environment friendly to remove NO using g-C3N4. Introducing new adsorption sites on the surface of g-C3N4 through microstructure control can alter the structure-activity relationship between g-C3N4 and gas molecules, thereby improving photocatalytic NO conversion activity and inhibiting NO2 generation. However, few review articles have focused on the microscopic effects of microstructural changes in g-C3N4 based materials on the adsorption and activation of NO and O2. This has important guiding significance for material design work in the field of NO conversion and strategies to fundamentally improve NO conversion activity and selectivity. Therefore, our work systematically summarizes the strategy of introducing adsorption and activation sites through microstructure control, and emphasizes the role of these sites in the photocatalytic NO conversion process. The aim is to clarify the influence of adsorption and activation sites on adsorption behavior and the correlation between these sites and reaction paths. Finally, the development trend and future prospects of increasing the level of g-C3N4 adsorption and activation in the field of photocatalytic NO conversion are introduced, which is expected to provide an important reference for the development and practical application of g-C3N4-based photocatalytic materials.

Abstract Image

求助全文
约1分钟内获得全文 求助全文
来源期刊
物理化学学报
物理化学学报 化学-物理化学
CiteScore
16.60
自引率
5.50%
发文量
9754
审稿时长
1.2 months
期刊介绍:
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信