Impacts of Aging and Relative Humidity on Properties of Biomass Burning Smoke Particles.

Abstract

Quantifying changes in the properties of smoke aerosols under varying conditions is important for understanding the health and environmental impacts of exposure to smoke. Smoke composition, aerosol liquid water content, effective density (ρ_eff), and other properties can change significantly as smoke travels through areas under different ambient conditions and over time. During this study, we measured changes in smoke composition and physical properties due to oxidative aging and exposure to humidity. We found that smoke aging led to SOA formation and increases in ratios of organic carbon to elemental carbon. Aerosol liquid water content increased with increasing relative humidity (RH), and aged smoke took up more water than fresh smoke at all humidity levels, likely due to a combination of changes in aerosol surface polarity at low and medium RH and increases in surface area with aging at high RH. Growth factors ranged from 1.06 ± 0.08 for fresh smoke at low RH to 1.32 ± 0.08 for aged smoke at high RH. Oxidative aging and exposure to humidity led to increases in ρ_eff. For 100 nm particles, ρ_eff ranged from ∼1.2 for fresh smoke at low RH to ∼1.6 for aged smoke at high RH. Results from these experiments suggest that exposure to humidity leads to smoke restructuring and compaction and/or changes in surface chemistry.