An ultra-high absorptivity solar absorber with excellent thermal radiation efficiency based on a metal–dielectric stacked structure

IF 2.9 3区 化学 Q3 CHEMISTRY, PHYSICAL
Yan Chen, Xiaoyun Wang, Sili Huang, Shiyi Song, Shanjun Chen, Jie Hou and Yan Xiong
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Abstract

Metamaterials hold great promise for application in the field of perfect absorbers due to their remarkable ability to manipulate electromagnetic waves. In this work, a full-spectrum ultra-wideband solar absorber with a multilayer metal–dielectric stacked structure is designed. Our absorber is simple and easy to manufacture, with Ti serving as the substrate, overlaid with Si3N4 spacer layers and four pairs of Ti–Si3N4 ring columns. It exhibits an average absorption rate of 98.48% from 280 to 4000 nm. The synergistic effects of cavity resonance (CR), surface plasmon resonance (SPR), and magnetic resonance (MR) effectively enhance the absorption performance. The impacts of different materials, stacked layers, and geometric parameters on the absorption performance are investigated, along with further analysis of the electromagnetic field distribution to study the physical mechanism for achieving high-efficiency absorption. Additionally, it is demonstrated that the absorber exhibits polarization-independent behavior under vertical incidence and maintains an average absorption rate of over 93% at a 50° incidence angle for transverse magnetic (TM) and transverse electric (TE) polarized light. Furthermore, the absorber achieves a total solar absorption rate of 98.07% across the entire spectrum, with a thermal radiation efficiency of over 99% and a photothermal conversion efficiency of 92.49% at 1000 K. To conclude, our absorber offers great possibilities for solar energy harvesting related applications.

Abstract Image

基于金属-介电材料叠层结构的超高吸收率太阳能吸收体,具有优异的热辐射效率
超材料具有操纵电磁波的卓越能力,因此在完美吸收器领域的应用前景十分广阔。在这项工作中,我们基于 FDTD 设计了一种多层金属-电介质叠层结构的全光谱超宽带太阳能吸收器。我们的吸收器结构简单、易于制造,以钛为基底,外覆 Si3N4 间隔层和四对 Ti-Si3N4 环柱。从 280 纳米到 4000 纳米,它的平均吸收率为 98.48%。空腔共振(CR)、表面等离子体共振(SPR)和磁共振(MR)的协同效应有效地提高了吸收性能。研究了不同材料、堆叠层和几何参数对吸收性能的影响,并进一步分析了电磁场分布,以研究实现高效吸收的物理机制。此外,研究还证明,该吸收器在垂直入射条件下表现出与偏振无关的特性,在 50° 入射角时,对 TM 和 TE 偏振光的平均吸收率超过 93%。总之,我们的吸收器为太阳能收集相关应用提供了巨大的可能性。
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来源期刊
Physical Chemistry Chemical Physics
Physical Chemistry Chemical Physics 化学-物理:原子、分子和化学物理
CiteScore
5.50
自引率
9.10%
发文量
2675
审稿时长
2.0 months
期刊介绍: Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.
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