Evaluation of Fenton-like reaction for sorption and degradation of kasugamycin in the presence of biochar.

IF 3.2 3区环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL

Environmental Geochemistry and Health Pub Date : 2025-01-15 DOI:10.1007/s10653-025-02357-4

Wei Zhang, Liqiang Cui, Jingwen Ma, Shuyan Cui, Guixiang Quan, Jinlong Yan, Fengfeng Sui, Hui Wang, Kiran Hina, Qaiser Hussain

{"title":"Evaluation of Fenton-like reaction for sorption and degradation of kasugamycin in the presence of biochar.","authors":"Wei Zhang, Liqiang Cui, Jingwen Ma, Shuyan Cui, Guixiang Quan, Jinlong Yan, Fengfeng Sui, Hui Wang, Kiran Hina, Qaiser Hussain","doi":"10.1007/s10653-025-02357-4","DOIUrl":null,"url":null,"abstract":"Although the use of biochar as an adsorbent for the removal of various pollutants from wastewater is well established, the use of biochar/modified biochar for the scavenging of antibiotics from aqueous media in the Fenton-like system receives less attention. The highest kasugamycin (KSM) adsorption capacity (5.0 mg g-1) was obtained from the pristine biochar at the lowest initial pH of 3 in Fenton-like system. The Fenton-like system improved the KSM adsorption capacity of pristine biochar by 222.2%, 169.9%, and 159.9% at 25 °C, 35 °C, and 45 °C comparing to control, respectively, and it also increased adsorption capacity by 97.4%, 63.8%, and 56.8% comparing to modified biochar. The amounts of biochar applied and the Fenton-like system affected KSM mineralization and degradation. The KSM degradation products had a significant amount of small molecular organic matter (m/z 384) and a tetrahydropyran structure that was difficult to degrade. The highly efficient degradation of KSM in Fenton-like system can be attributed to the generation of large amounts of hydroxyl radical (·OH) and functional groups (C=C, C=O, etc.).","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 2","pages":"50"},"PeriodicalIF":3.2000,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Geochemistry and Health","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1007/s10653-025-02357-4","RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}

引用次数: 0

Abstract

Although the use of biochar as an adsorbent for the removal of various pollutants from wastewater is well established, the use of biochar/modified biochar for the scavenging of antibiotics from aqueous media in the Fenton-like system receives less attention. The highest kasugamycin (KSM) adsorption capacity (5.0 mg g^-1) was obtained from the pristine biochar at the lowest initial pH of 3 in Fenton-like system. The Fenton-like system improved the KSM adsorption capacity of pristine biochar by 222.2%, 169.9%, and 159.9% at 25 °C, 35 °C, and 45 °C comparing to control, respectively, and it also increased adsorption capacity by 97.4%, 63.8%, and 56.8% comparing to modified biochar. The amounts of biochar applied and the Fenton-like system affected KSM mineralization and degradation. The KSM degradation products had a significant amount of small molecular organic matter (m/z 384) and a tetrahydropyran structure that was difficult to degrade. The highly efficient degradation of KSM in Fenton-like system can be attributed to the generation of large amounts of hydroxyl radical (·OH) and functional groups (C=C, C=O, etc.).

查看原文本刊更多论文

生物炭存在下Fenton-like反应对卡苏霉素吸附降解的评价。

尽管使用生物炭作为吸附剂去除废水中的各种污染物已经很好地建立了，但在类芬顿系统中，使用生物炭/改性生物炭清除水介质中的抗生素却很少受到关注。在Fenton-like体系中，初始pH最低为3时，原始生物炭对卡苏霉素（KSM）的吸附量最高，为5.0 mg g-1。在25°C、35°C和45°C条件下，Fenton-like体系对原始生物炭的KSM吸附量分别比对照提高了222.2%、169.9%和159.9%，吸附量比改性生物炭分别提高了97.4%、63.8%和56.8%。施用生物炭的量和Fenton-like体系影响KSM的矿化和降解。KSM降解产物含有大量的小分子有机物（m/z 384）和难以降解的四氢吡喃结构。类芬顿体系对KSM的高效降解可归因于大量羟基自由基（·OH）和官能团（C=C， C=O等）的生成。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Environmental Geochemistry and Health 环境科学-工程：环境

CiteScore

8.00

自引率

4.80%

发文量

279

审稿时长

4.2 months

期刊介绍： Environmental Geochemistry and Health publishes original research papers and review papers across the broad field of environmental geochemistry. Environmental geochemistry and health establishes and explains links between the natural or disturbed chemical composition of the earth’s surface and the health of plants, animals and people. Beneficial elements regulate or promote enzymatic and hormonal activity whereas other elements may be toxic. Bedrock geochemistry controls the composition of soil and hence that of water and vegetation. Environmental issues, such as pollution, arising from the extraction and use of mineral resources, are discussed. The effects of contaminants introduced into the earth’s geochemical systems are examined. Geochemical surveys of soil, water and plants show how major and trace elements are distributed geographically. Associated epidemiological studies reveal the possibility of causal links between the natural or disturbed geochemical environment and disease. Experimental research illuminates the nature or consequences of natural or disturbed geochemical processes. The journal particularly welcomes novel research linking environmental geochemistry and health issues on such topics as: heavy metals (including mercury), persistent organic pollutants (POPs), and mixed chemicals emitted through human activities, such as uncontrolled recycling of electronic-waste; waste recycling; surface-atmospheric interaction processes (natural and anthropogenic emissions, vertical transport, deposition, and physical-chemical interaction) of gases and aerosols; phytoremediation/restoration of contaminated sites; food contamination and safety; environmental effects of medicines; effects and toxicity of mixed pollutants; speciation of heavy metals/metalloids; effects of mining; disturbed geochemistry from human behavior, natural or man-made hazards; particle and nanoparticle toxicology; risk and the vulnerability of populations, etc.