Recent advances and perspectives in synthetic applications of silylboronates as silyl radical precursors†

IF 7.6 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Zhihua Cai, Qing-Qing Bu, Xi-Yu Wang, Shengchao Yang, Jian Zhou and Jin-Sheng Yu
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引用次数: 0

Abstract

Silylboronates, as powerful and versatile reagents, have been widely used in synthetic chemistry over the past few decades, due to their ability to incorporate silicon and boron atoms into organic molecules. With the rapid development of radical chemistry, the use of silylboronates as silyl radical precursors has recently become a research focus in organic synthesis. Significant achievements have been made in the synthetic applications of silylboronates as silyl radical sources for various C–Si and C–X bond forming transformations. This review summarizes these recent advances, discusses their advantages and limitations, and illustrates the synthetic chances still open for further research and applications in this emerging area.

Abstract Image

硅基硼酸盐作为硅基自由基前体的合成研究进展及展望
硅硼酸盐作为一种功能强大、用途广泛的试剂,由于其能够将硅和硼原子结合到有机分子中,在过去的几十年中被广泛用于合成化学。随着自由基化学的迅速发展,利用硅硼酸盐作为硅基自由基前体已成为近年来有机合成领域的研究热点。硅基硼酸盐作为硅基自由基源在各种C-Si和C-X成键转化中的合成应用取得了重大成就。本文综述了近年来的研究进展,讨论了它们的优点和局限性,并说明了在这一新兴领域中仍有进一步研究和应用的机会。
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来源期刊
Chemical Science
Chemical Science CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
14.40
自引率
4.80%
发文量
1352
审稿时长
2.1 months
期刊介绍: Chemical Science is a journal that encompasses various disciplines within the chemical sciences. Its scope includes publishing ground-breaking research with significant implications for its respective field, as well as appealing to a wider audience in related areas. To be considered for publication, articles must showcase innovative and original advances in their field of study and be presented in a manner that is understandable to scientists from diverse backgrounds. However, the journal generally does not publish highly specialized research.
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