Ye Gao, Lingli Wan, Yuqing Song, Shan Gao, Nan Yan, Fan Wu, Yanqiu Du
{"title":"Templated Self-Organization of Polymer-Tethered Gold Nanoparticles into Freestanding Superlattices at Liquid-Air Interface","authors":"Ye Gao, Lingli Wan, Yuqing Song, Shan Gao, Nan Yan, Fan Wu, Yanqiu Du","doi":"10.1039/d4cp04435e","DOIUrl":null,"url":null,"abstract":"Programmable organization of uniform organic/inorganic functional building blocks into large-scale ordered superlattices has attracted considerable attention since the bottom-up self-organization strategy opens up a robust and universal route for designing novel and multifunctional materials with advanced applications in memory storage devices, catalysis, photonic crystals, and biotherapy. Despite great efforts have been made in the construction of the superlattice materials, there still remains a challenge in the preparation of organic/inorganic hybrid superlattices with tunable dimensions and exotic configurations. Here, we report the spontaneous self-organization of polystyrene-tethered gold nanoparticles (AuNPs@PS) into freestanding organic/inorganic hybrid superlattices templated by the diethylene glycol-air interface. The resulting multilayer 3D superlattices exhibit hexagonally honeycomb and periodically tetrahedral lattice after the evaporation of AuNPs@PS building blocks at the liquid-air interface. Notably, a particular Moiré pattern originating from the twisted stacking of the adjacent layers is observed when the twist angle is 30°, leading to the exquisite quasi-crystalline packing with 12-fold rotational symmetry. In addition, the interparticle distance and gap within the 2D superlattice can be precisely regulated by adjusting the length of polymer segments, thereby generating the distinctive 3D graphene-skeleton configurations in the freestanding superlattice. This finding presents a highly efficient and versatile way to artificially produce multifunctional organic/inorganic hybrid superlattice materials with adjustable dimensions and internal configurations.","PeriodicalId":99,"journal":{"name":"Physical Chemistry Chemical Physics","volume":"113 1","pages":""},"PeriodicalIF":2.9000,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physical Chemistry Chemical Physics","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4cp04435e","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Programmable organization of uniform organic/inorganic functional building blocks into large-scale ordered superlattices has attracted considerable attention since the bottom-up self-organization strategy opens up a robust and universal route for designing novel and multifunctional materials with advanced applications in memory storage devices, catalysis, photonic crystals, and biotherapy. Despite great efforts have been made in the construction of the superlattice materials, there still remains a challenge in the preparation of organic/inorganic hybrid superlattices with tunable dimensions and exotic configurations. Here, we report the spontaneous self-organization of polystyrene-tethered gold nanoparticles (AuNPs@PS) into freestanding organic/inorganic hybrid superlattices templated by the diethylene glycol-air interface. The resulting multilayer 3D superlattices exhibit hexagonally honeycomb and periodically tetrahedral lattice after the evaporation of AuNPs@PS building blocks at the liquid-air interface. Notably, a particular Moiré pattern originating from the twisted stacking of the adjacent layers is observed when the twist angle is 30°, leading to the exquisite quasi-crystalline packing with 12-fold rotational symmetry. In addition, the interparticle distance and gap within the 2D superlattice can be precisely regulated by adjusting the length of polymer segments, thereby generating the distinctive 3D graphene-skeleton configurations in the freestanding superlattice. This finding presents a highly efficient and versatile way to artificially produce multifunctional organic/inorganic hybrid superlattice materials with adjustable dimensions and internal configurations.
期刊介绍:
Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions.
The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.