David O. Juma , Bernard Omondi , Sizwe J. Zamisa , Wisdom Munzeiwa
{"title":"(Z)-N-(2,6-Diisopropylphenyl)-1-[(2-methoxyphenyl)amino]methanimine oxide","authors":"David O. Juma , Bernard Omondi , Sizwe J. Zamisa , Wisdom Munzeiwa","doi":"10.1107/S241431462400988X","DOIUrl":null,"url":null,"abstract":"<div><div>The crystal structure of a zwitterionic, non-symmetric hydroxyformamidine derivative is described.</div></div><div><div>The molecular structure of the title compound, C<sub>20</sub>H<sub>26</sub>N<sub>2</sub>O<sub>2</sub> reveals non-co-planarity between the central formamidine backbone and each of the outer methoxy- and <em>i</em>-propyl- substituted benzene rings with dihedral angles of 7.88 (15) and 81.17 (15)°, respectively, indicating significant twists in the molecule. In the crystal, intermolecular C—H⋯O interactions, forming an <em>R</em><sup>3</sup><sub>4</sub>(30) graph set, occur within a two-dimensional layer that extends along the <em>ac</em> plane.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (246KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 10","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11660170/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624001093","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
The crystal structure of a zwitterionic, non-symmetric hydroxyformamidine derivative is described.
The molecular structure of the title compound, C20H26N2O2 reveals non-co-planarity between the central formamidine backbone and each of the outer methoxy- and i-propyl- substituted benzene rings with dihedral angles of 7.88 (15) and 81.17 (15)°, respectively, indicating significant twists in the molecule. In the crystal, intermolecular C—H⋯O interactions, forming an R34(30) graph set, occur within a two-dimensional layer that extends along the ac plane.
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