Synthesis and crystal structure of sodium (ethane-1,2-diyl)bis[(3-methoxypropyl)phosphinodithiolate] octahydrate

IF 0.5 Q4 CRYSTALLOGRAPHY

Acta Crystallographica Section E: Crystallographic Communications Pub Date : 2024-10-01 DOI:10.1107/S2056989024009642

Bryan P. Nell , David R. Tyler , Lev N. Zakharov , Dean H. Johnston

引用次数: 0

Abstract

In the title compound, the dianionic [CH₃O(CH₂)₃P(=S)(S—)CH₂CH₂P(=S)(S—)(CH₂)₃OCH₃]²⁻ ligand fragments are joined by a dicationic [Na₂(H₂O)₈]²⁺ cluster that includes the oxygen of the methoxypropyl unit of the ligand to form infinite chains.

The title compound, catena-poly[[triaquasodium]-di-μ-aqua-[triaquasodium]-μ-(ethane-1,2-diyl)bis[(3-methoxypropyl)phosphinodithiolato]], [Na₂(C₁₀H₂₂O₂P₂S₄)(H₂O)₈]_n, crystallizes in the triclinic space group P1. The dianionic [CH₃O(CH₂)₃P(=S)(S—)CH₂CH₂P(=S)(S—)(CH₂)₃OCH₃]²⁻ ligand fragments are joined by a dicationic [Na₂(H₂O)₈]²⁺ cluster that includes the oxygen of the methoxypropyl unit of the ligand to form infinite chains.

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（乙烷-1,2-二基）双-[（3-甲氧基-丙基）磷酸二硫醇酸钠]八水合物的合成及晶体结构。

标题化合物链-聚[[三水-钠]-二-μ-水-[三水-钠]-μ-（乙烷-1,2-二基）双-[（3-甲氧基-丙基）膦-二巯基]]，[Na2(C10H22O2P2S4)(H2O)8] n在三斜空间群P1中结晶。二阴离子[ch30 (CH2)3P(=S)(S-)CH2CH2P(=S)(S-)(CH2)3OCH3]2-配体片段由一个包含配体甲基-氧-丙基单元氧的指示[Na2(H2O)8]2+簇连接，形成无限链。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Acta Crystallographica Section E: Crystallographic Communications Chemistry-Chemistry (all)

CiteScore

1.90

自引率

0.00%

发文量

351

审稿时长

3 weeks

期刊介绍： Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.

Synthesis and crystal structure of sodium (ethane-1,2-di­yl)bis­[(3-meth­oxy­prop­yl)phosphinodi­thiol­ate] octa­hydrate

Abstract

Synthesis and crystal structure of sodium (ethane-1,2-diyl)bis[(3-methoxypropyl)phosphinodithiolate] octahydrate