Fluoroform (CHF3) Production from CF3CHO Photolysis and Implications for the Decomposition of Hydrofluoroolefins and Hydrochlorofluoroolefins in the Atmosphere

IF 14.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Joshua D. Thomson, Jyoti S. Campbell, Ethan B. Edwards, Christopher Medcraft, Klaas Nauta, Maria Paula Pérez-Peña, Jenny A. Fisher, David L. Osborn, Scott H. Kable, Christopher S. Hansen
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Abstract

Hydrofluoroolefins (HFOs) and hydrochlorofluoroolefins (HCFOs) are the leading synthetic replacements for compounds successively banned by the Montreal Protocol and amendments. HFOs and HCFOs readily decompose in the atmosphere to form fluorinated carbonyls, including CF3CHO in yields of up to 100%, which are then photolyzed. A long-standing issue, critical for the transition to safe industrial gases, is whether atmospheric decomposition of CF3CHO yields any quantity of CHF3 (HFC-23), which is one of the most environmentally hazardous greenhouse gases. This comprehensive experimental investigation employs purpose-built photoionization mass spectrometry, Fourier-transform infrared, and microwave spectroscopy techniques and confirms production of CHF3 following excitation at a tropospherically relevant wavelength (λ = 308 nm) and under atmospheric pressure conditions. Pressure-dependent CHF3 quantum (Φ) and molar (Y) yields are reported from Φ = Y = 0.16 ± 0.03 under collision-free conditions to Φ = (2.3 ± 0.3) × 10–4, Y = (1.17 ± 0.27) × 10–3 at 1 bar N2.

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来源期刊
CiteScore
24.40
自引率
6.00%
发文量
2398
审稿时长
1.6 months
期刊介绍: The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.
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