Xiao-Ping Lei, Qingfeng Wu, Xiangxi Zhang, Qing Zhou, Lingmin Yi
{"title":"Elucidate the mechanism behind the significant changes in photoluminescence behavior after powder compression into tablet","authors":"Xiao-Ping Lei, Qingfeng Wu, Xiangxi Zhang, Qing Zhou, Lingmin Yi","doi":"10.1039/d4cp03897e","DOIUrl":null,"url":null,"abstract":"Nonconventional luminogens have great potential applications in fields like anti-counterfeiting encryption. But so far, the photoluminescence quantum yield (PLQY) of most these powders is still relatively low and the persistent room temperature phosphorescence (p-RTP) emission is relatively weak. To improve their PLQY and p-RTP, pressing the powder into tablets has been preliminarily proven to be an effective method, but the specific mechanism has not been fully elucidated yet. Here, D-(+)-cellobiose has been chosen as the representative to solve the problem. The results showed that the PLQY and p-RTP lifetimes of the tablet of D-(+)-cellobiose were improved compared to the powder. By the mechanism of clustering-triggered emission (CTE) and theoretical calculations, it has been demonstrated that the enhanced molecular interactions after compression is the key reason, which resulting in the formation of cluster emission centers with stronger emission capabilities. And the combination of powder and tablet has been proven to be capable of advanced anti-counterfeiting encryption. The above results not only provide possible references for understanding the emission mechanism of small molecule and cellulose based emission materials, but also promote the process of more intuitive observation of emission centers for explaining emission mechanisms.","PeriodicalId":99,"journal":{"name":"Physical Chemistry Chemical Physics","volume":"32 1","pages":""},"PeriodicalIF":2.9000,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physical Chemistry Chemical Physics","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4cp03897e","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Nonconventional luminogens have great potential applications in fields like anti-counterfeiting encryption. But so far, the photoluminescence quantum yield (PLQY) of most these powders is still relatively low and the persistent room temperature phosphorescence (p-RTP) emission is relatively weak. To improve their PLQY and p-RTP, pressing the powder into tablets has been preliminarily proven to be an effective method, but the specific mechanism has not been fully elucidated yet. Here, D-(+)-cellobiose has been chosen as the representative to solve the problem. The results showed that the PLQY and p-RTP lifetimes of the tablet of D-(+)-cellobiose were improved compared to the powder. By the mechanism of clustering-triggered emission (CTE) and theoretical calculations, it has been demonstrated that the enhanced molecular interactions after compression is the key reason, which resulting in the formation of cluster emission centers with stronger emission capabilities. And the combination of powder and tablet has been proven to be capable of advanced anti-counterfeiting encryption. The above results not only provide possible references for understanding the emission mechanism of small molecule and cellulose based emission materials, but also promote the process of more intuitive observation of emission centers for explaining emission mechanisms.
期刊介绍:
Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions.
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