Impact of Bromine Complexing Agents and Battery Construction on Hydrogen–Bromine Redox Flow Battery Performance

IF 5.4 3区 材料科学 Q2 CHEMISTRY, PHYSICAL
Jingwen Zhang, Shiming Qiu*, Yinghong Wu*, Yifan Liu, Guangzhi Hu, Qian Liu, Jun Luo and Xijun Liu*, 
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Abstract

Hydrogen–bromine redox flow batteries (HBFBs) offer significant advantages in energy storage, including high energy capacity, efficient round-trip conversion, and low cost, positioning them as optimal solutions for grid applications. However, HBFBs are susceptible to issues such as self-discharge, the bromine shuttle effect, high Br2 vapor pressure, poisoning, and corrosion. Bromine complexing agents (BCAs) have been employed to mitigate these challenges, albeit with drawbacks such as reduced electrolyte conductivity, catalyst site blockage, and diffusion limitation. This review explores the impact of BCAs on the performance of HBFBs, focusing on cell structures such as electrolytes, membranes, and electrodes. Recent research progress in membrane materials and Pt catalysts is summarized to address these issues, and future prospects and challenges for high-performance HBFBs development are discussed.

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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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