{"title":"Visible Light Mediated CO2 Fixation Reactions to Produce Carbamates and Carbonates: A Comprehensive Review","authors":"Asmita Goswami, Monika Verma, Ajay Thakur, Ruchi Bharti, Renu Sharma","doi":"10.1002/jhet.4882","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>CO<sub>2</sub> is a significant greenhouse gas, and is considered as a copious renewable carbon reagent. From a synthetic perspective, it can be used as a sustainable and substitute C1 building block because of its nontoxic, nonflammable, and abundant nature. The transformation of a wide range of organic molecules with CO<sub>2</sub> into numerous efficient commodities is a defining feature of recent success in this sector. Because of its numerous applications, photocatalysts and visible light-mediated synthesis of carbamates and cyclic carbonates using CO<sub>2</sub> have drawn a lot of interest from researchers. This mini review mainly focusses on the different one-pot reactions that are proven to be efficacious for chemical fixation of CO<sub>2</sub> in producing industry-based compounds of carbamates and carbonates with the creation of C<span></span>O, C<span></span>H, C<span></span>C, and C<span></span>N bonds.</p>\n </div>","PeriodicalId":194,"journal":{"name":"Journal of Heterocyclic Chemistry","volume":"61 12","pages":"2050-2069"},"PeriodicalIF":2.0000,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Heterocyclic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/jhet.4882","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
CO2 is a significant greenhouse gas, and is considered as a copious renewable carbon reagent. From a synthetic perspective, it can be used as a sustainable and substitute C1 building block because of its nontoxic, nonflammable, and abundant nature. The transformation of a wide range of organic molecules with CO2 into numerous efficient commodities is a defining feature of recent success in this sector. Because of its numerous applications, photocatalysts and visible light-mediated synthesis of carbamates and cyclic carbonates using CO2 have drawn a lot of interest from researchers. This mini review mainly focusses on the different one-pot reactions that are proven to be efficacious for chemical fixation of CO2 in producing industry-based compounds of carbamates and carbonates with the creation of CO, CH, CC, and CN bonds.
期刊介绍：
The Journal of Heterocyclic Chemistry is interested in publishing research on all aspects of heterocyclic chemistry, especially development and application of efficient synthetic methodologies and strategies for the synthesis of various heterocyclic compounds. In addition, Journal of Heterocyclic Chemistry promotes research in other areas that contribute to heterocyclic synthesis/application, such as synthesis design, reaction techniques, flow chemistry and continuous processing, multiphase catalysis, green chemistry, catalyst immobilization and recycling.
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