Rh-Catalyzed trans-Divinylcyclopropane Rearrangement: An Approach to 1,5-Disubstituted 1,4-Cycloheptadienes

IF 4.9 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2024-12-19 DOI:10.1021/acs.orglett.4c03409

Han-Xiao Li, Zeyuan Shen, Jiguo Ma, Zhi-Xiang Yu

引用次数: 0

Abstract

Under mild conditions and without the need of inert gas protection, a Rh-catalyzed rearrangement of trans-divinylcyclopropanes to form 1,5-disubstituted 1,4-cycloheptadienes has been developed and is disclosed here. This reaction can expedite the synthesis of challenging seven-membered carbocycles.

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在温和条件下，无需惰性气体保护，Rh 催化的反式二乙烯基环丙烷重排生成 1,5- 二取代的 1,4- 环庚二烯的方法已经开发成功，现予以公布。该反应可加快具有挑战性的七元碳环的合成。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.