Nitric Acid Processing of Perovskite Concentrate under Atmospheric and Autoclave Conditions

IF 0.7 4区 工程技术 Q4 ENGINEERING, CHEMICAL
A. G. Artemenkov, L. G. Gerasimova, A. I. Nikolaev, Yu. G. Bychenya, E. S. Shchukina, E. V. Kuznetsova
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引用次数: 0

Abstract

The interaction of perovskite concentrate with nitric acid under atmospheric conditions and at an excess pressure was studied. High efficiency was achieved in the separation of components in the form of a solid phase (hydrated precipitate of titanium and rare metals) and a liquid phase containing calcium, rare-earth metals, and thorium. It was shown that the conditions of the acid treatment of the resulting precursors determine their structure and composition, which, in turn, determine the directions of their further processing to obtain final products. In particular, it was established that an increased pressure in the reaction zone causes rutilization of the hydrated precipitate, and therefore its further processing to produce titanium dioxide and rare metals should be carried out by chlorination.

Abstract Image

在大气和高压釜条件下用硝酸加工过氧化物硅酸盐浓缩物
研究了过氧化物精矿与硝酸在大气和超压条件下的相互作用。在分离固相(钛和稀有金属的水合沉淀)和含有钙、稀土金属和钍的液相形式的成分时,取得了很高的效率。研究表明,对所得到的前驱体进行酸处理的条件决定了它们的结构和组成,而结构和组成又决定了它们进一步加工以获得最终产品的方向。特别是,已确定反应区的压力增大会导致水合沉淀金红石化,因此应通过氯化进行进一步处理,以生产二氧化钛和稀有金属。
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来源期刊
CiteScore
1.20
自引率
25.00%
发文量
70
审稿时长
24 months
期刊介绍: Theoretical Foundations of Chemical Engineering is a comprehensive journal covering all aspects of theoretical and applied research in chemical engineering, including transport phenomena; surface phenomena; processes of mixture separation; theory and methods of chemical reactor design; combined processes and multifunctional reactors; hydromechanic, thermal, diffusion, and chemical processes and apparatus, membrane processes and reactors; biotechnology; dispersed systems; nanotechnologies; process intensification; information modeling and analysis; energy- and resource-saving processes; environmentally clean processes and technologies.
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