Review of Geopolymer Composites Synthesized Using Different Industrial By-products

M. J. Anju, M. Beulah, Alwyn Varghese
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Abstract

Managing the substantial volume of industrial waste is challenging due to diminishing landfill capacity and associated risks to people and the environment. The optimal approach is to repurpose or find alternative applications for these waste products. Previous studies have investigated using industrial waste and chemicals to enhance soil stability. Common binders like cement, while offering significant stabilization potential, raise concerns about economic feasibility and environmental impact. Recently, there’s a growing interest in low carbon emission cementing agents. This trend leads to using waste by-products for geopolymer binder production, potentially strengthening soft soil in an eco-friendly way. Unconfined compressive strength, vital in construction foundation design, has been a focus of extensive research to enhance soil strength over the years. This paper provides a brief overview of several studies that highlight the utilization of various industrial waste products in the synthesis of geopolymers. Also, this comprehensive review centers on investigations related to the application of geopolymers derived from industrial solid waste as a soil stabilizer. The review delves into the impact of various parameters, including different percentage mixes (%), molarity (M), temperature (T), curing time (days), on the unconfined compressive strength of the soil. It has been observed that, a variety of industrial by-products like Bagasse ash (BA), Blast furnace slag (BFS), Egg shell powder (ESP), Fly ash (FA), Ground Granulated Blast Furnace Slag (GGBS), Iron Ore Tailings (IOT), Metakaolin (MK), Palm Oil Fuel Ash (POFA), Recycled Asphalt Pavement (RAP), Rice husk ash (RHA), Red Mud (RM), etc. can serve as valuable source materials for geopolymerization. In most of the studies, the commonly utilized alkaline activator consists of a blend of sodium hydroxide and sodium silicate solution. The unconfined compressive strength of geopolymerized industrial waste products relies on specific parameters, including optimal alkaline concentration, activator liquid to raw material mass ratio, and sodium silicate to sodium hydroxide solution ratio. Diverse curing conditions are also necessary, varying with raw materials and activators.

Abstract Image

利用不同工业副产品合成土工聚合物复合材料综述
由于垃圾填埋场容量不断减少以及对人类和环境的相关风险,管理大量工业废物具有挑战性。最理想的方法是重新利用或寻找这些废物的替代用途。以前的研究已经研究了使用工业废料和化学品来增强土壤稳定性。水泥等常用粘合剂虽然具有显著的稳定潜力,但也引起了人们对经济可行性和环境影响的担忧。最近,人们对低碳排放固井剂的兴趣越来越大。这种趋势导致利用废弃副产品生产地聚合物粘合剂,可能以环保的方式加强软土。无侧限抗压强度在建筑基础设计中至关重要,多年来一直是提高土体强度的广泛研究热点。本文简要介绍了几种利用各种工业废料合成地聚合物的研究进展。此外,本文还对从工业固体废物中提取的地聚合物作为土壤稳定剂的研究进展进行了综述。该综述深入探讨了各种参数的影响,包括不同的混合百分比(%),摩尔浓度(M),温度(T),养护时间(天),对土壤的无侧限抗压强度。研究发现,甘蔗渣(BA)、高炉渣(BFS)、蛋壳粉(ESP)、粉煤灰(FA)、磨粒高炉渣(GGBS)、铁矿尾矿(IOT)、中高岭土(MK)、棕榈油燃料灰(POFA)、再生沥青面层(RAP)、稻壳灰(RHA)、赤泥(RM)等多种工业副产品均可作为有价值的地聚合原料。在大多数研究中,常用的碱性活化剂由氢氧化钠和硅酸钠溶液的混合物组成。地聚合工业废料的无侧限抗压强度取决于特定的参数,包括最佳碱浓度、活化剂液与原料质量比、水玻璃与氢氧化钠溶液比。不同的固化条件也是必要的,因原料和活化剂而异。
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