LuCl3/ZnI2 cocatalyzed 1,1-diborylation of terminal alkynes to 1,1-diborylalkenes with pinacolborane

IF 4.6 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Chemistry Frontiers Pub Date : 2024-12-09 DOI:10.1039/d4qo01796j

Rongrong Zhou, Wenli Wang, Jianping Zhang, Qi Wang, Ziyan Chen, Yinlin Shao, Fangjun Zhang

引用次数: 0

Abstract

A method was developed using LuCl3/ZnI2 to cocatalyze the 1,1-diboration of simple terminal alkynes, producing from moderate-to-good yields of 1,1-diborylalkenes. Large-scale synthesis and further transformations indicate that this method has potential practical applications. Isotopic labeling experiments, and control experiments are used to elucidate the reaction mechanism.

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来源期刊

Organic Chemistry Frontiers CHEMISTRY, ORGANIC-

CiteScore

7.90

自引率

11.10%

发文量

686

审稿时长

1 months

期刊介绍： Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.