{"title":"Hybrid plasmonic metamaterials: towards enhanced ultra broadband and wide-angle solar absorption for energy harvesting","authors":"Mahdi Rashki and Mohammad Reza Rakhshani","doi":"10.1039/D4CP03925D","DOIUrl":null,"url":null,"abstract":"<p >In this paper, we have investigated a hybrid metamaterial seven-layer solar absorber. The absorber has remarkable characteristics, including ultra-broadband perfect absorption capability, near-perfect absorption at wide angles, and insensitivity to polarization. The structure exhibits an average absorption of 98.05% across the spectral range of 300 to 5000 nm. Furthermore, the absorption bandwidth exceeding 90% spans more than 4950 nm. We have analyzed the absorptivity of the structure considering various optical mechanisms, including propagating surface plasmon resonance (SPR), local surface plasmon resonance (LSPR), guided-mode resonance (GMR), and magnetic resonance (MR). This solar absorber comprises two layers of SiO<small><sub>2</sub></small>–Fe and a layer of semi-oval TiN arrays. Despite specific geometric tolerances, it effectively maintains ultra-broad absorption performance from the visible to the mid-infrared (MIR) range. The structure demonstrates insensitivity to a wide range of polarization angles, up to approximately 65 degrees. This makes it a promising candidate for applications such as solar energy harvesting, thermal emitters, solar cells, and related technologies.</p>","PeriodicalId":99,"journal":{"name":"Physical Chemistry Chemical Physics","volume":" 2","pages":" 962-970"},"PeriodicalIF":2.9000,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physical Chemistry Chemical Physics","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/cp/d4cp03925d","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
In this paper, we have investigated a hybrid metamaterial seven-layer solar absorber. The absorber has remarkable characteristics, including ultra-broadband perfect absorption capability, near-perfect absorption at wide angles, and insensitivity to polarization. The structure exhibits an average absorption of 98.05% across the spectral range of 300 to 5000 nm. Furthermore, the absorption bandwidth exceeding 90% spans more than 4950 nm. We have analyzed the absorptivity of the structure considering various optical mechanisms, including propagating surface plasmon resonance (SPR), local surface plasmon resonance (LSPR), guided-mode resonance (GMR), and magnetic resonance (MR). This solar absorber comprises two layers of SiO2–Fe and a layer of semi-oval TiN arrays. Despite specific geometric tolerances, it effectively maintains ultra-broad absorption performance from the visible to the mid-infrared (MIR) range. The structure demonstrates insensitivity to a wide range of polarization angles, up to approximately 65 degrees. This makes it a promising candidate for applications such as solar energy harvesting, thermal emitters, solar cells, and related technologies.
期刊介绍:
Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions.
The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.