Harnessing the past: Vibration analysis of organic additives in ancient plasters for sustainable building solutions

IF 2.7 3区 化学 Q2 CHEMISTRY, ANALYTICAL
Bhushan Dhige , Manager Rajdeo Singh
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引用次数: 0

Abstract

This study investigates plant-based organic additives and grains used in ancient earthen plasters from the caves of Karla, Bhaja, Pitalkhora, Ellora, and Aurangabad in Maharashtra, India, highlighting their relevance for sustainable modern construction. Stereo microscopy, FTIR spectrophotometry, and phytochemical analysis identified rice husk, millet, wheat, Chenopodium album, Paspalum, barnyard millet, foxtail millet, and Fumaria seeds as key organic components. Starch grain analysis confirmed the presence of wheat, millet, and mung bean starches, while polarized light microscopy revealed distinctive birefringence patterns, such as the Maltese cross. FTIR analysis of solvent extractions identified natural compounds, including starches, gums, proteins, oils, waxes, and tree resins. These organic additives, especially rice husk, prevalent in Karla, Bhaja, and Pitalkhora samples, and the balanced composition of hemp fibers, seeds, and gums in Ellora samples, contributed significantly to the strength and durability of the plasters. The use of beeswax and tree resins as natural binders further underscores the ingenuity of these ancient techniques. This research not only highlights the botanical diversity in ancient construction but also draws critical connections to modern sustainable practices. The carbon-negative potential of these materials, combined with their renewability and resilience, aligns closely with contemporary green building strategies, offering inspiration for eco-friendly construction rooted in traditional Indian architecture.
利用过去:古代石膏中有机添加剂的振动分析,用于可持续建筑解决方案
本研究调查了印度马哈拉施特拉邦Karla、Bhaja、Pitalkhora、Ellora和Aurangabad洞穴中使用的古代泥塑中植物性有机添加剂和谷物,强调了它们与可持续现代建筑的相关性。立体显微镜、FTIR分光光度法和植物化学分析鉴定出稻壳、小米、小麦、Chenopodium album、Paspalum、稗子、foxtail millet和Fumaria种子是主要的有机成分。淀粉粒分析证实了小麦、小米和绿豆淀粉的存在,而偏振光显微镜显示出独特的双折射模式,如马耳他十字。溶剂萃取物的FTIR分析鉴定出天然化合物,包括淀粉、树胶、蛋白质、油、蜡和树树脂。这些有机添加剂,特别是稻壳,普遍存在于Karla, Bhaja和Pitalkhora样品中,以及Ellora样品中大麻纤维,种子和树胶的平衡组成,对石膏的强度和耐久性有显著贡献。蜂蜡和树树脂作为天然粘合剂的使用进一步强调了这些古老技术的独创性。这项研究不仅突出了古代建筑中的植物多样性,而且还将其与现代可持续实践联系起来。这些材料的碳负潜力,加上它们的可再生和弹性,与当代绿色建筑策略紧密结合,为植根于传统印度建筑的生态友好型建筑提供了灵感。
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来源期刊
Vibrational Spectroscopy
Vibrational Spectroscopy 化学-分析化学
CiteScore
4.70
自引率
4.00%
发文量
103
审稿时长
52 days
期刊介绍: Vibrational Spectroscopy provides a vehicle for the publication of original research that focuses on vibrational spectroscopy. This covers infrared, near-infrared and Raman spectroscopies and publishes papers dealing with developments in applications, theory, techniques and instrumentation. The topics covered by the journal include: Sampling techniques, Vibrational spectroscopy coupled with separation techniques, Instrumentation (Fourier transform, conventional and laser based), Data manipulation, Spectra-structure correlation and group frequencies. The application areas covered include: Analytical chemistry, Bio-organic and bio-inorganic chemistry, Organic chemistry, Inorganic chemistry, Catalysis, Environmental science, Industrial chemistry, Materials science, Physical chemistry, Polymer science, Process control, Specialized problem solving.
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