{"title":"Harnessing the past: Vibration analysis of organic additives in ancient plasters for sustainable building solutions","authors":"Bhushan Dhige , Manager Rajdeo Singh","doi":"10.1016/j.vibspec.2024.103751","DOIUrl":null,"url":null,"abstract":"<div><div>This study investigates plant-based organic additives and grains used in ancient earthen plasters from the caves of Karla, Bhaja, Pitalkhora, Ellora, and Aurangabad in Maharashtra, India, highlighting their relevance for sustainable modern construction. Stereo microscopy, FTIR spectrophotometry, and phytochemical analysis identified rice husk, millet, wheat, Chenopodium album, Paspalum, barnyard millet, foxtail millet, and Fumaria seeds as key organic components. Starch grain analysis confirmed the presence of wheat, millet, and mung bean starches, while polarized light microscopy revealed distinctive birefringence patterns, such as the Maltese cross. FTIR analysis of solvent extractions identified natural compounds, including starches, gums, proteins, oils, waxes, and tree resins. These organic additives, especially rice husk, prevalent in Karla, Bhaja, and Pitalkhora samples, and the balanced composition of hemp fibers, seeds, and gums in Ellora samples, contributed significantly to the strength and durability of the plasters. The use of beeswax and tree resins as natural binders further underscores the ingenuity of these ancient techniques. This research not only highlights the botanical diversity in ancient construction but also draws critical connections to modern sustainable practices. The carbon-negative potential of these materials, combined with their renewability and resilience, aligns closely with contemporary green building strategies, offering inspiration for eco-friendly construction rooted in traditional Indian architecture.</div></div>","PeriodicalId":23656,"journal":{"name":"Vibrational Spectroscopy","volume":"136 ","pages":"Article 103751"},"PeriodicalIF":2.7000,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Vibrational Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0924203124001048","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
This study investigates plant-based organic additives and grains used in ancient earthen plasters from the caves of Karla, Bhaja, Pitalkhora, Ellora, and Aurangabad in Maharashtra, India, highlighting their relevance for sustainable modern construction. Stereo microscopy, FTIR spectrophotometry, and phytochemical analysis identified rice husk, millet, wheat, Chenopodium album, Paspalum, barnyard millet, foxtail millet, and Fumaria seeds as key organic components. Starch grain analysis confirmed the presence of wheat, millet, and mung bean starches, while polarized light microscopy revealed distinctive birefringence patterns, such as the Maltese cross. FTIR analysis of solvent extractions identified natural compounds, including starches, gums, proteins, oils, waxes, and tree resins. These organic additives, especially rice husk, prevalent in Karla, Bhaja, and Pitalkhora samples, and the balanced composition of hemp fibers, seeds, and gums in Ellora samples, contributed significantly to the strength and durability of the plasters. The use of beeswax and tree resins as natural binders further underscores the ingenuity of these ancient techniques. This research not only highlights the botanical diversity in ancient construction but also draws critical connections to modern sustainable practices. The carbon-negative potential of these materials, combined with their renewability and resilience, aligns closely with contemporary green building strategies, offering inspiration for eco-friendly construction rooted in traditional Indian architecture.
期刊介绍:
Vibrational Spectroscopy provides a vehicle for the publication of original research that focuses on vibrational spectroscopy. This covers infrared, near-infrared and Raman spectroscopies and publishes papers dealing with developments in applications, theory, techniques and instrumentation.
The topics covered by the journal include:
Sampling techniques,
Vibrational spectroscopy coupled with separation techniques,
Instrumentation (Fourier transform, conventional and laser based),
Data manipulation,
Spectra-structure correlation and group frequencies.
The application areas covered include:
Analytical chemistry,
Bio-organic and bio-inorganic chemistry,
Organic chemistry,
Inorganic chemistry,
Catalysis,
Environmental science,
Industrial chemistry,
Materials science,
Physical chemistry,
Polymer science,
Process control,
Specialized problem solving.