Synthesis and characterization of thermal properties of poly(p-cumylphenyl methacrylate-co-methoxyethyl methacrylate) copolymers

IF 4 2区化学 Q2 CHEMISTRY, PHYSICAL

Journal of Molecular Structure Pub Date : 2024-11-24 DOI:10.1016/j.molstruc.2024.140890

E. Parthiban , S. Sudarsan , A. Charles , S. Mohan , A. Kumar , A. Kistan

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Abstract

The poly(p-cumylphenyl methacrylate-co-methoxyethyl methacrylate) copolymers has been fabricated in a simple way. The p-cumylphenyl methacrylate and methoxy methacrylate were polymerized by free radical mechanism using benzoyl peroxide as an initiator. The synthesized copolymers were confirmed by Fourier transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance (¹H NMR) and carbon nuclear magnetic resonance (¹³C NMR) spectral techniques. The heat durability of copolymers has been investigated by Thermogravimetric analysis (TGA), derivative thermogravimetry, and differential thermal analysis (DTA). The glass transition temperature (Tg) of copolymer was carried out using differential scanning calorimetry (DSC). The scanning electron microscopy (SEM) was utilized to observe the surface texture and morphology roughness of copolymers. The obtained copolymers have possess an excellent coating property, anti-corrosive property, and optical property. Hence, these can be utilize in different way like solar, sensors, polymer conductivity, battery electrolytes, nanotechnology, viscosity, and biomedical.

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来源期刊

Journal of Molecular Structure 化学-物理化学

CiteScore

7.10

自引率

15.80%

发文量

2384

审稿时长

45 days

期刊介绍： The Journal of Molecular Structure is dedicated to the publication of full-length articles and review papers, providing important new structural information on all types of chemical species including: • Stable and unstable molecules in all types of environments (vapour, molecular beam, liquid, solution, liquid crystal, solid state, matrix-isolated, surface-absorbed etc.) • Chemical intermediates • Molecules in excited states • Biological molecules • Polymers. The methods used may include any combination of spectroscopic and non-spectroscopic techniques, for example: • Infrared spectroscopy (mid, far, near) • Raman spectroscopy and non-linear Raman methods (CARS, etc.) • Electronic absorption spectroscopy • Optical rotatory dispersion and circular dichroism • Fluorescence and phosphorescence techniques • Electron spectroscopies (PES, XPS), EXAFS, etc. • Microwave spectroscopy • Electron diffraction • NMR and ESR spectroscopies • Mössbauer spectroscopy • X-ray crystallography • Charge Density Analyses • Computational Studies (supplementing experimental methods) We encourage publications combining theoretical and experimental approaches. The structural insights gained by the studies should be correlated with the properties, activity and/ or reactivity of the molecule under investigation and the relevance of this molecule and its implications should be discussed.