Assessing the heat storage potential of zeolitic imidazolate frameworks (ZIFs) using water and ethanol as working fluids

IF 4.3 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Ciara Byrne , Matjaž Mazaj , Nataša Zabukovec Logar
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Abstract

Zeolitic imidazolate frameworks (ZIFs) are comprised of transition metal cations such as Zn(II) and imidazolate-based ligands. Due to their inherent properties, including large surface areas, well-defined and stable porous structure, ZIFs hold significant promise for adsorption applications. Sorption-based heat storage and transformation with porous materials and water as working fluid has been recently recognized as one of the most promising approaches to address more efficient use of energy. In this study, we examined seven different ZIFs (ZIF-8, ZIF-62, ZIF-71, ZIF-74, ZIF-76, ZIF-90 and ZIF-93) and their heat storage potential using water and ethanol as working fluids. It has been demonstrated that storage performance is governed by several factors, including pore dimensions, type and distribution of functional groups on imidazolate ligands, chemical stability of the framework as well as the type of the working fluid. Ethanol sorption data demonstrates inflection points in sorption isotherms at lower relative pressures, enhancement of uptakes for ZIFs with hydrophobic properties, but lower desorption enthalpies if compared to water sorption. We found that ZIF-93 was the most promising material for both working fluids.

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来源期刊
Materials Chemistry and Physics
Materials Chemistry and Physics 工程技术-材料科学:综合
CiteScore
8.70
自引率
4.30%
发文量
1515
审稿时长
69 days
期刊介绍: Materials Chemistry and Physics is devoted to short communications, full-length research papers and feature articles on interrelationships among structure, properties, processing and performance of materials. The Editors welcome manuscripts on thin films, surface and interface science, materials degradation and reliability, metallurgy, semiconductors and optoelectronic materials, fine ceramics, magnetics, superconductors, specialty polymers, nano-materials and composite materials.
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