Numerical simulation on the effect of contact angle on the permeation of emulsions through a membrane in premix membrane emulsification

IF 5.3 2区 化学 Q2 CHEMISTRY, PHYSICAL
Jophous Mugabi , Jae-Ho Jeong
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Abstract

The effect of membrane wettability on emulsion permeation behavior in premix membrane emulsification was investigated. The Volume of Fluid (VOF) method was employed to simulate the permeation of a single droplet through pore channel constrictions of a microporous membrane. The wettability was adjusted by varying the wall contact angle between 0 and 180 degrees.
For contact angles less than 90 degrees, lower angles resulted in complete wetting of the membrane, leading to lower capillary pressures but higher critical pressures for the dispersed phase to permeate through the membrane. Conversely, as the contact angles increase, the capillary pressures increase while the critical pressure required for permeation reduces due to decreased wettability of the channel walls. For contact angles greater than 90 degrees, the deformed droplets did not wet the channel walls and reformed into spherical droplets upon exiting the channel. In this regime, the critical pressure for droplet permeation showed an inverse relationship with the contact angle. The capillary pressure was associated with the continuous water phase that wetted the channel walls, rather than with the droplet itself. As the contact angle increased, the degree of wetting by the continuous phase also increased, resulting in the lowest critical pressure observed at a contact angle of 180 degrees. Optimizing the contact angle can minimize process energy requirements while ensuring efficient droplet passage through the pore constriction. This contributes to more sustainable and cost-effective processes in various industries such as emulsification, oil separation, and microfiltration.

Abstract Image

预混合膜乳化中接触角对乳剂膜渗透影响的数值模拟
研究了预混合膜乳化中膜润湿性对乳液渗透行为的影响。采用流体体积法(VOF)模拟了单个液滴通过微孔膜孔道收缩的渗透过程。通过改变壁面接触角,在0 ~ 180度之间调节润湿性。当接触角小于90度时,较低的接触角导致膜完全湿润,导致毛细管压力较低,但分散相渗透膜的临界压力较高。相反,随着接触角的增加,毛细管压力增加,而由于通道壁润湿性降低,渗透所需的临界压力降低。当接触角大于90度时,变形的液滴不润湿通道壁面,在离开通道后重新形成球形液滴。在这种情况下,液滴渗透的临界压力与接触角呈反比关系。毛细管压力与湿润通道壁的连续水相有关,而不是与液滴本身有关。随着接触角的增加,连续相的润湿程度也增加,导致在180度接触角处观察到最低的临界压力。优化接触角可以最大限度地减少过程能量需求,同时确保有效的液滴通过孔隙收缩。这有助于在乳化、油分离和微过滤等各个行业中实现更具可持续性和成本效益的工艺。
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来源期刊
Journal of Molecular Liquids
Journal of Molecular Liquids 化学-物理:原子、分子和化学物理
CiteScore
10.30
自引率
16.70%
发文量
2597
审稿时长
78 days
期刊介绍: The journal includes papers in the following areas: – Simple organic liquids and mixtures – Ionic liquids – Surfactant solutions (including micelles and vesicles) and liquid interfaces – Colloidal solutions and nanoparticles – Thermotropic and lyotropic liquid crystals – Ferrofluids – Water, aqueous solutions and other hydrogen-bonded liquids – Lubricants, polymer solutions and melts – Molten metals and salts – Phase transitions and critical phenomena in liquids and confined fluids – Self assembly in complex liquids.– Biomolecules in solution The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include: – Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.) – Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.) – Light scattering (Rayleigh, Brillouin, PCS, etc.) – Dielectric relaxation – X-ray and neutron scattering and diffraction. Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.
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