Meha Bhargava, Sonia Ali, Mamta Guleria, Jyoti Agarwal
{"title":"Phenolic -OH-Induced Fluorescence and Chemoselectivity in a Triptycene-Based <i>trans</i>-Azo Oligomer for Sensing Applications.","authors":"Meha Bhargava, Sonia Ali, Mamta Guleria, Jyoti Agarwal","doi":"10.1021/acs.jpcb.4c05081","DOIUrl":null,"url":null,"abstract":"<p><p>A novel triptycene-based <i>trans</i>-azo fluorescent oligomer exhibiting phenolic groups has been designed. The presence of phenolic -OH in conjugation with the azo group rendered the oligomer fluorescence active by keto-enol tautomerism, which was evidenced by quenching the fluorescence intensity of <b>TP1</b> in 1 M aq. NaOH. A green synthetic protocol was employed to synthesize this oligomer as a dark-brown solid, and it was characterized by using diverse analytical tools such as FTIR, <sup>13</sup>C-CPMAS NMR, GPC, FESEM, EDS, TGA, and PXRD techniques. FESEM and PXRD confirmed its existence as amorphous nanoclusters. The oligomer displayed efficient chemosensing properties toward the detection of picric acid with the LOD value of 391 nM. The specific recognition of PA in the presence of other explosives and the results of real water sample analysis further indicated the high efficacy of the <b>TP1</b> as a chemosensor.</p>","PeriodicalId":60,"journal":{"name":"The Journal of Physical Chemistry B","volume":" ","pages":"12227-12236"},"PeriodicalIF":2.8000,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Journal of Physical Chemistry B","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1021/acs.jpcb.4c05081","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/27 0:00:00","PubModel":"Epub","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
A novel triptycene-based trans-azo fluorescent oligomer exhibiting phenolic groups has been designed. The presence of phenolic -OH in conjugation with the azo group rendered the oligomer fluorescence active by keto-enol tautomerism, which was evidenced by quenching the fluorescence intensity of TP1 in 1 M aq. NaOH. A green synthetic protocol was employed to synthesize this oligomer as a dark-brown solid, and it was characterized by using diverse analytical tools such as FTIR, 13C-CPMAS NMR, GPC, FESEM, EDS, TGA, and PXRD techniques. FESEM and PXRD confirmed its existence as amorphous nanoclusters. The oligomer displayed efficient chemosensing properties toward the detection of picric acid with the LOD value of 391 nM. The specific recognition of PA in the presence of other explosives and the results of real water sample analysis further indicated the high efficacy of the TP1 as a chemosensor.
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An essential criterion for acceptance of research articles in the journal is that they provide new physical insight. Please refer to the New Physical Insights virtual issue on what constitutes new physical insight. Manuscripts that are essentially reporting data or applications of data are, in general, not suitable for publication in JPC B.
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