Hydrothermal synthesis of BiFe2O4 heterostructure for photodegradation of dye and biological implications

Sahana Nagarakere Chandranna , Dhananjay Purushotham , Abhilash Mavinakere Ramesh , Srikantaswamy Shivanna
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Abstract

The extensive use of dyes in the textile industry can be hazardous to human health. Commonly used organic dyes are dangerous and non-biodegradable, which greatly increases the contamination of industrial effluent. Because of their smaller size, greater surface area, and wider band gap, nano-sized metal oxides have drawn interest in heterogeneous photocatalysis as a solution to this problem. These substances are essential for the deterioration of dyes, especially when exposed to sunlight. Within this framework, the investigation aimed to clarify the photocatalytic effectiveness of nanoscale metal oxides by using hydrothermally synthesised bismuth ferrite (BiFe2O4) nanoparticles. The evaluation focused on how the organic dye molecule degraded in the presence of sun radiation. The materials based on BiFe2O4, which are recognized for their multi-ferroic characteristics, showed encouraging outcomes for quick photocatalytic degradation. The outcomes showed that organic dyes might be photo degraded under solar light irradiation with remarkable efficiency. Additionally, the BiFe2O4 hetrostructure showed promise in the removal of lead (Pb), Iron (Fe), copper (Cu), and chromium (Cr). The spectroscopic characterization techniques that were employed to investigate the physical properties of the synthesised nanoparticles included X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDX), UV-Vis spectroscopy, photoluminescence (PL), Brunauer-Emmett-Teller (BET) analysis, dynamic light scattering (DLS), and Raman spectroscopy. The characterization analysis confirmed the structure, shape, functional group, and optical properties of NPs. Using antimicrobial assays, the study also investigated the biological activity of the synthesised compounds.
用于染料光降解的 BiFe2O4 异质结构的水热合成及其生物学意义
纺织业大量使用染料会危害人类健康。常用的有机染料既危险又不可生物降解,大大增加了工业废水的污染。纳米级金属氧化物因其更小的尺寸、更大的表面积和更宽的带隙,作为解决这一问题的异相光催化技术而备受关注。这些物质对染料的劣化至关重要,尤其是在暴露于阳光下时。在此框架内,本研究旨在通过使用水热合成的铁氧体铋(BiFe2O4)纳米粒子,阐明纳米级金属氧化物的光催化效果。评估的重点是有机染料分子在太阳辐射下的降解情况。基于 BiFe2O4 的材料具有公认的多铁性特征,在快速光催化降解方面显示出令人鼓舞的结果。研究结果表明,在太阳光照射下,有机染料可能会被光降解,而且效率极高。此外,BiFe2O4 Hetrostructure 在去除铅(Pb)、铁(Fe)、铜(Cu)和铬(Cr)方面也显示出良好的前景。为研究合成纳米粒子的物理性质而采用的光谱表征技术包括 X 射线衍射 (XRD)、扫描电子显微镜 (SEM)、傅立叶变换红外光谱 (FT-IR)、能量色散 X 射线光谱 (EDX)、紫外可见光谱 (UV-Vis)、光致发光 (PL)、Brunauer-Emmett-Teller (BET) 分析、动态光散射 (DLS) 和拉曼光谱。表征分析证实了 NPs 的结构、形状、官能团和光学特性。该研究还利用抗菌试验研究了合成化合物的生物活性。
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