Stereo selective total synthesis of (3R),(5R)-5‑hydroxy-de-O-methyllasiodiplodin

IF 2.218 Q2 Chemistry
Saikam Narendra , Paul Douglas Sanasi , Krishnakanth Reddy Leleti , Kiran Kumar Murahari
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引用次数: 0

Abstract

An efficient stereoselective total synthesis of (3R),(5R)-5‑hydroxy-de-O-methyllasiodiplodin has been accomplished starting from commercially available materials. The key steps involved in this synthesis are Grignard reaction, Yamaguchi esterification and RCM reaction.
(3R),(5R)-5-羟基-脱-O-甲基壳斗素的立体选择性全合成
从市场上可买到的材料开始,我们完成了 (3R)、(5R)-5-羟基-脱-O-甲基壳斗素的高效立体选择性全合成。该合成的关键步骤包括格氏反应、山口酯化和 RCM 反应。
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来源期刊
Chemical Data Collections
Chemical Data Collections Chemistry-Chemistry (all)
CiteScore
6.10
自引率
0.00%
发文量
169
审稿时长
24 days
期刊介绍: Chemical Data Collections (CDC) provides a publication outlet for the increasing need to make research material and data easy to share and re-use. Publication of research data with CDC will allow scientists to: -Make their data easy to find and access -Benefit from the fast publication process -Contribute to proper data citation and attribution -Publish their intermediate and null/negative results -Receive recognition for the work that does not fit traditional article format. The research data will be published as ''data articles'' that support fast and easy submission and quick peer-review processes. Data articles introduced by CDC are short self-contained publications about research materials and data. They must provide the scientific context of the described work and contain the following elements: a title, list of authors (plus affiliations), abstract, keywords, graphical abstract, metadata table, main text and at least three references. The journal welcomes submissions focusing on (but not limited to) the following categories of research output: spectral data, syntheses, crystallographic data, computational simulations, molecular dynamics and models, physicochemical data, etc.
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