Relation between critical exponent of the conductivity and the morphological exponents of percolation theory.

Abstract

A central unsolved problem in percolation theory over the past five decades has been whether there is a direct relationship between the critical exponents that characterize the power-law behavior of the transport properties near the percolation threshold, particularly the effective electrical conductivity σ_{e}, and the exponents that describe the morphology of percolation clusters. The problem is also relevant to the relation between the static exponents of percolation clusters and the critical dynamics of spin waves in dilute ferromagnets, the elasticity of gels and composite solids, hopping conductivity in semiconductors, solute transport in porous media, and many others. We propose an approach to address the problem by showing that the contributions to σ_{e} can be decomposed into several groups representing the structure of percolation networks, including their mass and tortuosity, as well as constrictivity that describes the fluctuations in the driving potential gradient along the transport paths. The decomposition leads to a relationship between the critical exponent t of σ_{e} and other percolation exponents in d dimensions, t/ν=(d-D_{bb})+2(D_{op}-1)+d_{C}, where ν, D_{bb}, D_{op}, and d_{C} are, respectively, the correlation length exponent, the fractal dimensions of the backbones and the optimal paths, and the exponent that characterizes the constrictivity. Numerical simulations in two and three dimensions, as well as analytical results in d=1 and d=6, the upper critical dimension of percolation, validate the relationship. We, therefore, believe that the solution to the 50-year-old problem has been derived.