{"title":"Experimental Modeling of Boron-10 Isotope Enrichment during Chemical Exchange in a Liquid–Liquid System","authors":"P. I. Ivanov, A. V. Khoroshilov, N. S. Panyukova","doi":"10.1134/S0036024424702182","DOIUrl":null,"url":null,"abstract":"<p>The authors continue their set of studies on the separation of boron isotopes by means of chemical exchange in liquid–liquid systems using tri-<i>n</i>-octylamine as the main component of the organic phase. Degree of separation <i>K</i> = 1.0961 ± 0.0016 was obtained using experimental modeling of the operation of a rectangular cascade for separating boron isotopes in a 30-h long period of separation in the mode of product extraction. The obtained data are used to determine period τ = 19–21 h of concentration needed to reach a steady state when operating with product extraction at maximum degree of separation <i>K</i><sub>m</sub> = 1.109. The time needed to reach a steady state is τ = 130–160 h when operating in the mode without product extraction, which corresponds to maximum degree of separation <i>K</i><sub>m</sub> = 1.131.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":"98 12","pages":"2891 - 2896"},"PeriodicalIF":0.7000,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024424702182","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The authors continue their set of studies on the separation of boron isotopes by means of chemical exchange in liquid–liquid systems using tri-n-octylamine as the main component of the organic phase. Degree of separation K = 1.0961 ± 0.0016 was obtained using experimental modeling of the operation of a rectangular cascade for separating boron isotopes in a 30-h long period of separation in the mode of product extraction. The obtained data are used to determine period τ = 19–21 h of concentration needed to reach a steady state when operating with product extraction at maximum degree of separation Km = 1.109. The time needed to reach a steady state is τ = 130–160 h when operating in the mode without product extraction, which corresponds to maximum degree of separation Km = 1.131.
期刊介绍:
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.