Yueshen Zhou, Dongsheng Yuan and Kiyoshi Shimamura
{"title":"Bulk crystal growth and characterization of non-centrosymmetric single crystal CaTa4O11†","authors":"Yueshen Zhou, Dongsheng Yuan and Kiyoshi Shimamura","doi":"10.1039/D4CE00949E","DOIUrl":null,"url":null,"abstract":"<p >Despite that the reported CaO–Ta<small><sub>2</sub></small>O<small><sub>5</sub></small> phase diagram indicates its incongruent melting behavior, for the first time, we found that bulk single crystals of non-centrosymmetric CaTa<small><sub>4</sub></small>O<small><sub>11</sub></small> can be grown successfully by the floating-zone method. The as-grown crystal rods (<em>Φ</em> 5–6 mm) have a black and colorless transparent appearance in Ar and O<small><sub>2</sub></small> growth atmospheres, respectively. Consequently, the O<small><sub>2</sub></small> atmosphere was selected to optimize its bulk crystal growth. The CaTa<small><sub>4</sub></small>O<small><sub>11</sub></small> single crystals show good crystallinity with a symmetric X-ray rocking curve for the 004 diffraction peak with an FWHM of 72′′. For this new hexagonal bulk single crystal, its anisotropic optical, dielectric, and thermal properties were characterized. The crystal has a UV cut-off edge at 272 nm and a visible transmittance of ∼75% till 800 nm. When excited by both 254 nm UV and X-ray, it shows a broad-band emission with a peak wavelength of around 427 nm. The dielectric constants <em>ε</em><small><sub>11</sub></small> and <em>ε</em><small><sub>33</sub></small> were found to be 30 and 52.3, respectively at 1 kHz. Meanwhile, the thermal conductivity along the <em>c</em>-axis is 5.69 W m<small><sup>−1</sup></small> K<small><sup>−1</sup></small>, which is 1.8 times higher than that along the <em>a</em>-axis, which measures 3.19 W m<small><sup>−1</sup></small> K<small><sup>−1</sup></small> at room temperature.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 45","pages":" 6432-6437"},"PeriodicalIF":2.6000,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce00949e","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Despite that the reported CaO–Ta2O5 phase diagram indicates its incongruent melting behavior, for the first time, we found that bulk single crystals of non-centrosymmetric CaTa4O11 can be grown successfully by the floating-zone method. The as-grown crystal rods (Φ 5–6 mm) have a black and colorless transparent appearance in Ar and O2 growth atmospheres, respectively. Consequently, the O2 atmosphere was selected to optimize its bulk crystal growth. The CaTa4O11 single crystals show good crystallinity with a symmetric X-ray rocking curve for the 004 diffraction peak with an FWHM of 72′′. For this new hexagonal bulk single crystal, its anisotropic optical, dielectric, and thermal properties were characterized. The crystal has a UV cut-off edge at 272 nm and a visible transmittance of ∼75% till 800 nm. When excited by both 254 nm UV and X-ray, it shows a broad-band emission with a peak wavelength of around 427 nm. The dielectric constants ε11 and ε33 were found to be 30 and 52.3, respectively at 1 kHz. Meanwhile, the thermal conductivity along the c-axis is 5.69 W m−1 K−1, which is 1.8 times higher than that along the a-axis, which measures 3.19 W m−1 K−1 at room temperature.