Petrography and geochemistry of volcanic rocks of the Kulf-Amba area, in the Northwestern Ethiopian plateau: Implication for petrogenesis of felsic volcanic suites

Abstract

The Kulf-Amba area, located on the Northwestern Ethiopian plateau, is primarily composed of Cenozoic volcanic rocks with minor intertrappean sediments. To understand the petrogenesis of these rocks, we conducted field investigations, petrographic studies, and geochemical analyses. The main volcanic products include basalt (upper and lower), rhyolite lava flows, rhyolitic ignimbrite, volcanic glass, and agglomeratic tuff. Basalts exhibit aphanitic, porphyritic, and glomerophyric textures, with phenocryst of olivine, Ca-rich plagioclase, clinopyroxene, and Fe-Ti oxides. Felsic rocks display porphyritic, aphyric, and glassy textures, with phenocryst of quartz, alkali feldspar, and Fe-Ti oxides. Geochemical data reveal a bimodal composition. The mafic rocks resemble high titaniferous (HT2) basalts of Northwestern Ethiopia and are classified as transitional to tholeiitic. Felsic rocks are primarily peralkaline comendites. The mafic rocks exhibit a depleted heavy rare earth element (HREE) pattern with (Dy/Yb)_N = 1.75–2.02 and enriched light rare earth element (LREE) values with (Ce/Yb)_N = 7.16–9.26, without a significant negative Eu anomaly. Enrichment in LREE with (Ce/Yb)_N = 6.27–15.03 and flat HREE with (Dy/Yb)_N = 1.23–1.79, with varying Eu negative anomaly are characteristics of the felsic volcanic rocks, indicating removal of plagioclase throughout their evolutionary process. The consistent Nb/Ta (17.29–23.67 ppm) and Zr/Hf (37.53–45.08 ppm) ratios in both mafic and felsic rocks suggest that fractional crystallization was the dominant process in their formation, with small crystal contamination. The primitive mantle-normalized variation diagram for the mafic rocks reveals LREE enrichment and HREE depletion, indicating garnet in the source. Melting models using primitive mantle normalized values of Sm/Yb vs. La/Sm ratios further confirm garnet's presence and suggest a low degree (2%) of partial melting a source with less than 2% of garnet. The trace element signatures and geochemical modelling of the mafic lavas indicate a plume-related origin, potentially related to the Afar mantle plume.