Design and evaluations of nano-ceramic electrolytes used for solid-state lithium battery

Sajid Bashir, Jingbo Louise Liu
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Abstract

We explored safer, superior energy storage solutions by investigating all-solid-state electrolytes with high theoretical energy densities of 3860 mAh g−1, corresponding to the Li-metal anode. Despite challenges like dendrite growth, we synthesized ceramic-based electrolytes using green chemistry. These non-doped and doped electrolytes with F-, Ce-, and Mo demonstrated notable ionic conductivity (0.15–0.54 S cm−1) and durability. By customizing nanostructured materials, we improved battery performance, surpassing the conductivity of commercial electrolytes.

Abstract Image

用于固态锂电池的纳米陶瓷电解质的设计与评估
我们通过研究理论能量密度高达 3860 mAh g-1 的全固态电解质(相当于锂金属阳极),探索了更安全、更优越的储能解决方案。尽管面临枝晶生长等挑战,我们还是利用绿色化学合成了陶瓷基电解质。这些未掺杂和掺杂 F-、Ce- 和 Mo 的电解质具有显著的离子导电性(0.15-0.54 S cm-1)和耐久性。通过定制纳米结构材料,我们提高了电池性能,超越了商用电解质的导电性。
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