Gold(I)-Catalyzed 6-exo-dig Hydroamination/7-endo-dig Cycloisomerization Domino Approach to 3,7a-Diazacyclohepta[jk]fluorene Derivatives

IF 5.4 3区材料科学 Q2 CHEMISTRY, PHYSICAL

ACS Applied Energy Materials Pub Date : 2024-11-14 DOI:10.1021/acs.orglett.4c03926

Lu Yang, Fukai Xie, Lianjie Zhang, Jipeng Wei, Jiaji Li, Xiang Li, Jiayue Fu, Bin Lin, Maosheng Cheng, Yongxiang Liu

引用次数: 0

Abstract

A series of 3,7a-diazacyclohepta[jk]fluorene derivatives were synthesized via a gold(I)-catalyzed 6-exo-dig hydroamination/7-endo-dig cycloisomerization domino method. The method exhibits a broad substrate scope, and a plausible mechanism has been proposed. The efficacy of this strategy is further validated by the successful derivatization of 3,7a-diazacyclohepta[jk]fluorene.

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金（I）催化 6-exo-dig 氢氨化/7-endo-dig 环异构化多米诺方法制备 3,7a-二氮杂环庚烷[jk]芴衍生物

通过金（I）催化的 6-exo-dig hydroamination/7-endo-dig cycloisomerization domino 法合成了一系列 3,7a-diazacyclohepta[jk]fluorene 衍生物。该方法具有广泛的底物范围，并提出了合理的机理。3,7a-diazacyclohepta[jk]fluorene 的成功衍生进一步验证了这一策略的有效性。

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来源期刊

ACS Applied Energy Materials Materials Science-Materials Chemistry

CiteScore

10.30

自引率

6.20%

发文量

1368

期刊介绍： ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.