Electrochemical Synthesis of Nitrite and Nitrate via Cathodic Oxygen Activation in Liquefied Ammonia

IF 14.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of the American Chemical Society Pub Date : 2024-11-04 DOI:10.1021/jacs.4c1027910.1021/jacs.4c10279

Moritz Lukas Krebs, and , Ferdi Schüth*,

引用次数: 0

Abstract

The electrochemical oxidation of ammonia (NH₃) enables decentralized small-scale synthesis of nitrate (NO₃^–) and nitrite (NO₂^–) under ambient conditions by directly utilizing renewable energy. Yet, their electrosynthesis has been restricted to aqueous media and low ammonia concentrations. For the first time, we demonstrate here a strategy enabling the direct electrooxidation of liquefied NH₃ to NO₃^– and NO₂^– by using molecular oxygen, achieving combined Faraday efficiencies above 40%.

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在液化氨中通过阴极氧活化电化学合成亚硝酸盐和硝酸盐

氨（NH3）的电化学氧化可直接利用可再生能源，在环境条件下分散地小规模合成硝酸盐（NO3-）和亚硝酸盐（NO2-）。然而，它们的电合成一直局限于水介质和低氨浓度。我们在此首次展示了一种利用分子氧将液化 NH3 直接电氧化为 NO3- 和 NO2-的策略，其综合法拉第效率超过 40%。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of the American Chemical Society 化学-化学综合

CiteScore

24.40

自引率

6.00%

发文量

2398

审稿时长

1.6 months

期刊介绍： The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.