Weather-Resistant Organosilicate Coatings with Improved Water Resistance

IF 1.4 4区 化学 Q4 CHEMISTRY, PHYSICAL
L. N. Krasil’nikova, Ya. A. Khamidulin, V. I. Voshchikov, E. D. Vasilieva, A. K. Kychkin, Chi Van Nguyen, A. M. Nikolaev, Yu. E. Gorshkova, O. A. Shilova
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Abstract

Currently, composites based on glass fibers and epoxy resins are successfully used to produce various structural elements. Such structures often serve under extreme conditions of both the Far North and the tropics, with such conditions having a destructive effect on the materials causing degradation of their properties. In this case, water resistance is an important characteristic of the materials. One of the ways to protect such materials is the use of organosilicate coatings (OSCs) obtained on the basis of organosilicon varnishes and highly dispersed hydrosilicates. This article presents the results of laboratory studies and field tests carried out in areas with very cold, as well as tropical savannah and subequatorial climates, of composite and metallic materials protected with OSCs. The objects of the studies are OSCs based on a binder, KO-921 varnish modified with the aim to improve weather resistance, primarily, moisture resistance, with poly(dimethylsiloxane) and epoxy resin. Water absorption, contact angle, and hardness of OSCs have been studied as depending on the composition of the polymer binders, and the optimal concentrations of the precursors have been determined. The results of field tests have shown that the developed OSCs retain their water-repellent properties during long-term exposure in different climatic conditions, thereby confirming their applicability to protecting various materials under the conditions of both tropics and the Far North.

Abstract Image

耐候性更强的有机硅涂料
目前,以玻璃纤维和环氧树脂为基础的复合材料已成功用于制造各种结构元件。这些结构通常在极北和热带的极端条件下使用,这些条件会对材料产生破坏性影响,导致其性能下降。在这种情况下,防水性是材料的一个重要特性。保护此类材料的方法之一是使用以有机硅清漆和高度分散的水硅酸盐为基础的有机硅涂料(OSC)。本文介绍了在极寒地区以及热带稀树草原和亚赤道气候条件下,对使用有机硅酸盐涂层保护的复合材料和金属材料进行实验室研究和实地测试的结果。研究对象是以粘合剂 KO-921 清漆为基础的 OSCs,该清漆经聚(二甲基硅氧烷)和环氧树脂改性,旨在提高耐候性,主要是防潮性。我们研究了有机碳酸钙的吸水性、接触角和硬度与聚合物粘合剂成分的关系,并确定了前体的最佳浓度。实地测试结果表明,所开发的 OSCs 在不同气候条件下长期暴露时仍能保持其憎水特性,从而证实了它们在热带和极北地区条件下保护各种材料的适用性。
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来源期刊
Colloid Journal
Colloid Journal 化学-物理化学
CiteScore
2.20
自引率
18.20%
发文量
36
审稿时长
6-12 weeks
期刊介绍: Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.
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