Recent Studies on Alkoxides Grafted Mesoporous Silica Materials as Catalysts in Meerwein–Ponndorf–Verley Reductions: A Review

IF 1.3 4区化学 Q4 CHEMISTRY, PHYSICAL

Kinetics and Catalysis Pub Date : 2024-09-28 DOI:10.1134/S0023158424601931

Burcu Uysal Karataş, Birsen Sengul Oksal

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Abstract

This review provides a comprehensive survey of the preparation and application of homogeneous and heterogeneous boron and indium alkoxide catalysts and typical Meerwein–Ponndorf–Verley (MPV) reduction process techniques that are usually employed in the production of alcohol. A significant number of preparation and application methods are now available for various heterogeneous catalysts synthesized with some mesoporous silica nanoparticles. In this review article, preparation, characterization, application and advantages of boron and indium alkoxides grafted metal-free mesoporous heterogeneous catalysts are discussed. Also, recent research on applying mesoporous MCM-41 and SBA-15 to heterogeneous catalysis in synthesizing heterogeneous MPV catalysts has been reviewed. The potential heterogeneous catalysts that could be derived from the grafting of alkoxides on mesoporous materials, methods of preparing solid boron and indium alkoxide catalysts, as well as reusability and leaching analysis are discussed in detail. We think that the development of new, environmentally friendly, efficient, and selective catalytic procedures for carbonyl reduction and alcohol formation, represents a fundamental research aim in synthetic chemistry. In this context, this review can make an important contribution to organic synthesis.

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将接枝介孔二氧化硅材料作为 Meerwein-Ponndorf-Verley 还原反应催化剂的最新研究：综述

本综述全面介绍了均相和异相硼与铟氧化物催化剂的制备和应用，以及通常用于生产酒精的典型 Meerwein-Ponndorf-Verley (MPV) 还原工艺技术。目前，有大量的制备和应用方法可用于与某些介孔二氧化硅纳米颗粒合成的各种异相催化剂。本综述文章讨论了硼和铟烷氧基接枝无金属介孔异相催化剂的制备、表征、应用和优势。此外，文章还综述了将介孔 MCM-41 和 SBA-15 应用于异相催化合成异相 MPV 催化剂的最新研究。详细讨论了在介孔材料上接枝烷氧基化合物可能衍生出的异相催化剂、固体硼和铟烷氧基化合物催化剂的制备方法以及可重复使用性和浸出分析。我们认为，开发新型、环保、高效和选择性催化程序用于羰基还原和醇类生成，是合成化学的一个基本研究目标。在这方面，本综述可为有机合成做出重要贡献。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Kinetics and Catalysis 化学-物理化学

CiteScore

2.10

自引率

27.30%

发文量

审稿时长

6-12 weeks

期刊介绍： Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.