Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings.

Abstract

Scented volatile chemical products (sVCPs) are frequently used indoors. We conducted field measurements in a residential building to investigate new particle formation (NPF) from sVCP emissions. State-of-the-art instrumentation was used for real-time monitoring of indoor atmospheric nanocluster aerosol (NCA; 1-3 nm particles) size distributions and terpene mixing ratios. We integrated our NCA measurements with a comprehensive material balance model to analyze sVCP-nucleated indoor NCA dynamics. Our results reveal that sVCPs significantly increase indoor terpene mixing ratios (10-1,000 ppb), exceeding those in outdoor forested environments. The emitted terpenes react with indoor atmospheric O₃ and initiate indoor NPF, resulting in nucleation rates as high as ∼10⁵ cm^-3 s^-1 and condensational growth rates up to 300 nm h^-1; these are orders of magnitude higher than those reported during outdoor NPF events. Notably, high particle nucleation rates significantly increase indoor atmospheric NCA concentrations (10⁵-10⁸ cm^-3), and high growth rates drive their survival and growth to sizes that efficiently reach the deepest regions of the human respiratory system. We found sVCP-nucleated NCA to cause respiratory exposures and dose rates comparable to or exceeding those from primary aerosol sources such as gas stoves and diesel engines, highlighting their significant impact on indoor atmospheric environments.