{"title":"Structures of the First Epitaxial Layer Created in Colloidal Heteroepitaxy.","authors":"Masahide Sato","doi":"10.1021/acs.jpcb.4c06191","DOIUrl":null,"url":null,"abstract":"<p><p>Brownian dynamics simulations have been performed to investigate the structural dependence of the first epitaxial layer in colloidal heteroepitaxy. When the epitaxial particles were larger than the substrate particles and the interactions were dominated by the depletion force, a hexagonal structure formed on a closely packed hexagonal substrate. The orientation of this hexagonal structure varied with the size ratio of the epitaxial to substrate particles to make the interaction between the substrate and epitaxial particles strong. When the sizes of the substrate and epitaxial particles were similar, long-period structures formed instead of hexagonal structures to strengthen the interaction between the substrate and epitaxial layer at the expense of the interaction between particles in the first epitaxial layer.</p>","PeriodicalId":60,"journal":{"name":"The Journal of Physical Chemistry B","volume":null,"pages":null},"PeriodicalIF":2.8000,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Journal of Physical Chemistry B","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1021/acs.jpcb.4c06191","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Brownian dynamics simulations have been performed to investigate the structural dependence of the first epitaxial layer in colloidal heteroepitaxy. When the epitaxial particles were larger than the substrate particles and the interactions were dominated by the depletion force, a hexagonal structure formed on a closely packed hexagonal substrate. The orientation of this hexagonal structure varied with the size ratio of the epitaxial to substrate particles to make the interaction between the substrate and epitaxial particles strong. When the sizes of the substrate and epitaxial particles were similar, long-period structures formed instead of hexagonal structures to strengthen the interaction between the substrate and epitaxial layer at the expense of the interaction between particles in the first epitaxial layer.
期刊介绍:
An essential criterion for acceptance of research articles in the journal is that they provide new physical insight. Please refer to the New Physical Insights virtual issue on what constitutes new physical insight. Manuscripts that are essentially reporting data or applications of data are, in general, not suitable for publication in JPC B.