Modeling the aspect ratio of commercial catalysts

Jean W. L. Beeckman
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Abstract

Mathematical modeling plays a diverse and crucial role in the chemical industry and academia. This manuscript describes how the physical and mechanical engineering disciplines help the commercialization of catalysts from evaluation to scale-up and manufacturing. Forming and shaping the catalyst is the first basic step in the catalyst manufacturing industry. Part A shows some of the classic process methods that are employed for this purpose. Catalyst extrudates require proper engineering and process control of their aspect ratio. Catalyst extrudates with a high aspect ratio tend to yield a low reactor fill due to a loose packing. Catalyst extrudates with a low aspect ratio tend to yield high pressure drop. Part B introduces the tensile strength of the catalyst in order to predict the aspect ratio of catalyst extrudates in commercial plants. A force-balance between the tensile strength of the catalyst and the impact forces due to collision experienced during manufacture leads to the dimensionless group B e . The group B e allows to introduce and quantify the severity of equipment and the severity of entire commercial plants.

Abstract Image

Abstract Image

商用催化剂长径比建模
数学建模在化学工业和学术界发挥着多样化的关键作用。本手稿介绍了物理和机械工程学科如何帮助催化剂从评估到放大和制造的商业化过程。催化剂的成型和塑造是催化剂制造业的第一个基本步骤。A 部分介绍了为此采用的一些经典工艺方法。催化剂挤出物需要适当的工程设计和长径比工艺控制。长径比高的催化剂挤出物由于填料松散,反应器填充率往往较低。长径比低的催化剂挤出物往往会产生较高的压降。B 部分介绍了催化剂的拉伸强度,以预测商业装置中催化剂挤出物的长径比。催化剂的拉伸强度与生产过程中碰撞产生的冲击力之间的力平衡可得出无量纲 B e。通过 B e 组,可以引入并量化设备的严重性和整个商业工厂的严重性。
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