{"title":"Photoluminescence and thermally stimulated luminescence properties of Sr3Y(PO4)3 single crystals doped with dy","authors":"Haruaki Ezawa , Kai Okazaki , Yuma Takebuchi , Takumi Kato , Daisuke Nakauchi , Noriaki Kawaguchi , Takayuki Yanagida","doi":"10.1016/j.solidstatesciences.2024.107715","DOIUrl":null,"url":null,"abstract":"<div><div>Sr<sub>3</sub>Y(PO<sub>4</sub>)<sub>3</sub> (SYPO) is recognized as a highly promising material for dosimetry applications, owing to its dosimetric properties. In this work, we synthesized the SYPO single crystals doped with 0.1, 0.5, 1, and 5 % Dy using the floating zone furnace to evaluate the photoluminescence and thermally stimulated luminescence (TSL) characteristics. All the SYPO single crystals doped with Dy exhibited emission peaks at 480, 580, 670, and 760 nm in PL and TSL spectra. These emission peaks were typical for the 4f–4f transitions of Dy<sup>3+</sup> ions. The SYPO single crystal doped with 0.1 % Dy displayed a glow peak in the TSL glow curve at 70 °C. The SYPO single crystals doped with 0.5, 1, and 5 % Dy showed two glow peaks at approximately 70 and 110 °C. The SYPO single crystal doped with 0.5 % Dy exhibited the highest TSL intensity with a lower detection limit of 0.1 mGy. The SYPO single crystal doped with 0.5 % Dy showed a spatial resolution of 50.0 μm after X-ray irradiation of 1Gy.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"157 ","pages":"Article 107715"},"PeriodicalIF":3.4000,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solid State Sciences","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1293255824002802","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Sr3Y(PO4)3 (SYPO) is recognized as a highly promising material for dosimetry applications, owing to its dosimetric properties. In this work, we synthesized the SYPO single crystals doped with 0.1, 0.5, 1, and 5 % Dy using the floating zone furnace to evaluate the photoluminescence and thermally stimulated luminescence (TSL) characteristics. All the SYPO single crystals doped with Dy exhibited emission peaks at 480, 580, 670, and 760 nm in PL and TSL spectra. These emission peaks were typical for the 4f–4f transitions of Dy3+ ions. The SYPO single crystal doped with 0.1 % Dy displayed a glow peak in the TSL glow curve at 70 °C. The SYPO single crystals doped with 0.5, 1, and 5 % Dy showed two glow peaks at approximately 70 and 110 °C. The SYPO single crystal doped with 0.5 % Dy exhibited the highest TSL intensity with a lower detection limit of 0.1 mGy. The SYPO single crystal doped with 0.5 % Dy showed a spatial resolution of 50.0 μm after X-ray irradiation of 1Gy.
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