{"title":"Experimental Study on Spontaneous Combustion of Low Rank Coal Containing High Sulfur in Goaf Atmosphere","authors":"Nan Jia","doi":"10.3103/S0361521924700290","DOIUrl":null,"url":null,"abstract":"<p>To study the effect of pyrite on coal spontaneous combustion characteristics in low-rank coal under an oxygen atmosphere in goaf, this paper selected PZ brown coal impregnated with pyrite and its reaction products and monitored the changes in the generation of characteristic gases CO and CO<sub>2</sub> during the programmed heating process of coal samples. The experiment found that oxygen concentration has the greatest impact on the spontaneous combustion characteristics of coal with added Fe<sup>3+</sup>. When the oxygen concentration in goaf coal increases to 9%, the promotion rate of high sulfur coal spontaneous combustion is the highest, which easily increases the range of goaf spontaneous combustion risk areas. When the temperature rises to 60°C, the catalytic effect of pyrite reaction products on coal spontaneous combustion is greatly enhanced. Through FTIR testing, it was found that Fe<sup>3+</sup> ions, as strong oxidative free radicals, promote the reaction of –CH<sub>2</sub>–, –COOH, and –OH in coal at low oxygen concentrations, leading to a further increase in the tendency of coal to self ignite at low oxygen concentrations.</p>","PeriodicalId":779,"journal":{"name":"Solid Fuel Chemistry","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solid Fuel Chemistry","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.3103/S0361521924700290","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
To study the effect of pyrite on coal spontaneous combustion characteristics in low-rank coal under an oxygen atmosphere in goaf, this paper selected PZ brown coal impregnated with pyrite and its reaction products and monitored the changes in the generation of characteristic gases CO and CO2 during the programmed heating process of coal samples. The experiment found that oxygen concentration has the greatest impact on the spontaneous combustion characteristics of coal with added Fe3+. When the oxygen concentration in goaf coal increases to 9%, the promotion rate of high sulfur coal spontaneous combustion is the highest, which easily increases the range of goaf spontaneous combustion risk areas. When the temperature rises to 60°C, the catalytic effect of pyrite reaction products on coal spontaneous combustion is greatly enhanced. Through FTIR testing, it was found that Fe3+ ions, as strong oxidative free radicals, promote the reaction of –CH2–, –COOH, and –OH in coal at low oxygen concentrations, leading to a further increase in the tendency of coal to self ignite at low oxygen concentrations.
期刊介绍:
The journal publishes theoretical and applied articles on the chemistry and physics of solid fuels and carbonaceous materials. It addresses the composition, structure, and properties of solid fuels. The aim of the published articles is to demonstrate how novel discoveries, developments, and theories may be used in improved analysis and design of new types of fuels, chemicals, and by-products. The journal is particularly concerned with technological aspects of various chemical conversion processes and includes papers related to geochemistry, petrology and systematization of fossil fuels, their beneficiation and preparation for processing, the processes themselves, and the ultimate recovery of the liquid or gaseous end products.