Di-μ-adipato-κ4O1,O1′:O6,O6′-bis­[(2,2′-di­pyridyl­amine-κ2N,N′)zinc(II)] trihydrate

IUCrData Pub Date : 2024-09-01 DOI:10.1107/S2414314624009064
Fatima Setifi , Zouaoui Setifi , Thang Pham Chien , Mohammad Hadi Al-Douh , Abderezak Addala
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引用次数: 0

Abstract

The title dinuclear and centrosymmetric complex mol­ecule exhibits a highly distorted octa­hedral O4N2 coordination set about the central zinc(II) atom.
The title compound, [Zn2(C6H8O4)2(C10H9N3)2]·3H2O or {Zn2[(C5H4N)2NH]2[μ-(CH2)4(COO)2]2}·3H2O, was separ­ated from the solvothermal reaction of zinc(II) sulfate hepta­hydrate, 2,2′-di­pyridyl­amine and sodium adipate. The dinuclear metal complex has a centrosymmetric structure, with the ZnII atom adopting a highly distorted octa­hedral coordination sphere composed of four oxygen atoms from bridging adipato ligands and two pyridine nitro­gen atoms. In the crystal, the title compound aggregates into a tri-periodic supra­molecular structure through inter­molecular hydrogen-bonding networks of the form O—H⋯O and N—H⋯O.
  1. Download: Download high-res image (235KB)
  2. Download: Download full-size image
二-μ-己二胺-κ4 O 1,O 1':O 6,O 6'-双-[(2,2'-二-吡啶基-胺-κ2 N,N')锌(II)]三水合物。
标题化合物[Zn2(C6H8O4)2(C10H9N3)2]-3H2O或{Zn2[(C5H4N)2NH]2[μ-(CH2)4(COO)2]2}-3H2O是从七水合硫酸锌(II)、2,2'-二吡啶基胺和己二酸钠的溶热反应中分离出来的。该双核金属复合物具有中心对称结构,其中 ZnII 原子采用高度扭曲的八面体配位圈,该配位圈由桥接己二酸配体的四个氧原子和两个吡啶硝基原子组成。在晶体中,标题化合物通过分子间 O-H⋯O 和 N-H⋯O 形式的氢键网络聚集成一个三周期超分子结构。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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CiteScore
0.30
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