Crystal structure and Hirshfeld surface analysis of trichlorido(1,10-phenanthroline-κ2N,N′)phenyltin(IV)

IF 0.5 Q4 CRYSTALLOGRAPHY

Acta Crystallographica Section E: Crystallographic Communications Pub Date : 2024-09-01 DOI:10.1107/S2056989024009150

Tarek Benlatreche , Mohamed Abdellatif Bensegueni , Georges Dénès , Stéphane Golhen , Hocine Merazig

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引用次数: 0

Abstract

The title compound, which was obtained by the reaction between 1,10-phenanthroline and phenyltin trichloride in methanol, exhibits intramolecular interactions involving the chlorine and hydrogen atoms. Crystal cohesion is ensured by intermolecular C—H⋯Cl hydrogen bonds, as well as Y—X⋯π and π-stacking interactions

The title compound, [Sn(C₆H₅)Cl₃(C₁₂H₈N₂)], which was obtained by the reaction between 1,10-phenanthroline and phenyltin trichloride in methanol, exhibits intramolecular hydrogen-bonding interactions involving the chlorine and hydrogen atoms. Crystal cohesion is ensured by intermolecular C—H⋯Cl hydrogen bonds, as well as Y—X⋯π and π-stacking interactions involving three different aromatic rings with centroid–centroid distances of 3.6605 (13), 3.9327 (14) and 3.6938 (12) Å]. Hirshfeld surface analysis and the associated two-dimensional fingerprint plots reveal significant contributions from H⋯H (30.7%), Cl⋯H/H⋯Cl (32.4%), and C⋯H/H⋯C (24.0%) contacts to the crystal packing while the C⋯C (6.2%), C⋯Cl/Cl⋯C (4.1%), and N⋯H/H⋯N (1.7%) interactions make smaller contributions.

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三氯-(1,10-菲罗啉-κ2 N,N')苯基锡(IV)的晶体结构和希尔施菲尔德表面分析。

标题化合物[Sn(C6H5)Cl3(C12H8N2)]是由 1,10-菲罗啉和苯基三氯化锡在甲醇中反应得到的，其分子内的氢键相互作用涉及氯原子和氢原子。分子间的 C-H⋯Cl 氢键以及涉及三个不同芳香环的 Y-X⋯π 和 π-stacking 相互作用确保了晶体的内聚力，其中心-中心距离分别为 3.6605 (13)、3.9327 (14) 和 3.6938 (12) Å]。Hirshfeld 表面分析和相关的二维指纹图显示，H⋯H（30.7%）、Cl⋯H/H⋯Cl（32.4%）和 C⋯H/H⋯C （24.0%）接触对晶体堆积的贡献较大，而 C⋯C （6.2%）、C⋯Cl/Cl⋯C （4.1%）和 N⋯H/H⋯N （1.7%）相互作用的贡献较小。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Acta Crystallographica Section E: Crystallographic Communications Chemistry-Chemistry (all)

CiteScore

1.90

自引率

0.00%

发文量

351

审稿时长

3 weeks

期刊介绍： Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.

Crystal structure and Hirshfeld surface analysis of tri­chlorido­(1,10-phenanthroline-κ2N,N′)phenyltin(IV)

Abstract

Crystal structure and Hirshfeld surface analysis of trichlorido(1,10-phenanthroline-κ2N,N′)phenyltin(IV)