A Negatively Curved Nanographene with Four Embedded Heptagons

IF 14.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of the American Chemical Society Pub Date : 2024-09-27 DOI:10.1021/jacs.4c09185

Sven M. Elbert, Owen T. A. Paine, Tobias Kirschbaum, Moritz P. Schuldt, Laura Weber, Frank Rominger, Michael Mastalerz

引用次数: 0

Abstract

Negatively curved nanographenes are considered as cutouts of three-dimensional fully sp²-hybridized carbon allotropes such as Schwarzites. Here we present the synthesis of a C₇₆ cut-out of the Schwarzite 8-4-1-p proposed by Lenosky et al. and investigate its optical as well as electrochemical properties. Furthermore, supramolecular interactions with fullerenes C₆₀ and C₇₀ were studied.

Abstract Image

查看原文本刊更多论文

带有四个嵌入式七芒星的负弯曲纳米石墨烯

负弯曲纳米石墨被认为是三维全 sp2 杂化碳同素异形体（如施瓦茨石）的切口。在此，我们介绍了 Lenosky 等人提出的施瓦兹石 8-4-1-p 的 C76 切面的合成，并研究了其光学和电化学特性。此外，我们还研究了与富勒烯 C60 和 C70 的超分子相互作用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of the American Chemical Society 化学-化学综合

CiteScore

24.40

自引率

6.00%

发文量

2398

审稿时长

1.6 months

期刊介绍： The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.