Burcu Karataş , Mustafa Akyildiz , Nail Yildirim , Tolga Oyman
{"title":"Formation conditions and geochemistry of the Tütün Tepeleri (Baskil-Elazig/Türkiye) Fe-oxide-Cu-Au (IOCG) mineralization","authors":"Burcu Karataş , Mustafa Akyildiz , Nail Yildirim , Tolga Oyman","doi":"10.1016/j.jafrearsci.2024.105407","DOIUrl":null,"url":null,"abstract":"<div><div>The Tütün Tepeleri Fe-Oxide-Cu-Au (IOCG) mineralization is located in the Eastern Taurus Mountains (Baskil-Elazığ/Turkey) and it is associated with Baskil magmatites (diorite, gabbro and tonalite) cut by Late Cretaceous Bilaser Tepe magmatites (quartized diorite, granite, granodiorite, tonalite porphyry, monzosyenite, monzonite, aplite and diorite porphyry). Baskil Magmatites are Coniacian-Santonian (82–86 Ma), calc-alkaline in character and I-type. Bilaser Tepe Magmatics are Campanian (73–74 Ma) and represent an extensional environment after the collision of oceanic arc and the Taurus platform. In this study, the Sodic-calcic alteration zone in the Tütün Tepeleri region, which was determined as Porphyry type mineralization by different researchers, was determined for the first time and the mineralizations were evaluated in terms of Fe-Oxide-Cu-Au (IOCG) deposits. Three types of alteration zones have been identified in the region, including the sodic-calcic alteration zone. These are sodic-calcic (tremolite-actinolite, albite, epidote, chlorite, magnetite), potassic (biotite, quartz, chlorite, K-feldspar, anhydrite) and sericitic (sericite, carbonate, quartz, chlorite, illite) alterations. Sodic-calcic alteration is more widespread in the region than >1 km<sup>2</sup>, reaches thicknesses of 500 m, and is occasionally overlain by potassic alterations, just like similar Fe-Oxide-Cu-Au (IOCG) deposits in the world. Tütün Tepeleri mineralizations are in the form of rare magnetite veins with intense magnetite dispersion within the sodic-calcic alteration developed in diorites. Mineral paragenesis is in the form of magnetite, molybdenite, pyrite, arsenopyrite, chalcopyrite, sphalerite, galena, hematite, malachite and azurite, and Ti content in magnetites is determined as 0.13–0.64%. Fe content is 20.13% on average. Formation temperatures in fluid inclusions measured in ore-bearing quartz veins are 320.3 °C on average and salinity is 11.32% NaCl equivalent on average. Isotope analysis results of these mineralizations show δ<sup>34</sup>S<sub>pyrite</sub> = 6–8.9; δ<sup>34</sup>S<sub>c.pyrite</sub> = 3.8–5.5; δ<sup>18</sup>O<sub>quartz</sub> was determined in the range of 10.8–13.2 and δD = (−37) – (−53). When the alteration types determined with isotope analysis results showing that the mineralization occurred in a magmatic-hydrothermal system, the low Ti content in the magnetites, the formation temperature and salinity values are evaluated together, it was anticipated that Tütün Tepeleri mineralization is an example of Fe-Oxide-Cu-Au (IOCG) deposits formed in a hydrothermal-magmatic system.</div></div>","PeriodicalId":14874,"journal":{"name":"Journal of African Earth Sciences","volume":"220 ","pages":"Article 105407"},"PeriodicalIF":2.2000,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of African Earth Sciences","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1464343X24002401","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GEOSCIENCES, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The Tütün Tepeleri Fe-Oxide-Cu-Au (IOCG) mineralization is located in the Eastern Taurus Mountains (Baskil-Elazığ/Turkey) and it is associated with Baskil magmatites (diorite, gabbro and tonalite) cut by Late Cretaceous Bilaser Tepe magmatites (quartized diorite, granite, granodiorite, tonalite porphyry, monzosyenite, monzonite, aplite and diorite porphyry). Baskil Magmatites are Coniacian-Santonian (82–86 Ma), calc-alkaline in character and I-type. Bilaser Tepe Magmatics are Campanian (73–74 Ma) and represent an extensional environment after the collision of oceanic arc and the Taurus platform. In this study, the Sodic-calcic alteration zone in the Tütün Tepeleri region, which was determined as Porphyry type mineralization by different researchers, was determined for the first time and the mineralizations were evaluated in terms of Fe-Oxide-Cu-Au (IOCG) deposits. Three types of alteration zones have been identified in the region, including the sodic-calcic alteration zone. These are sodic-calcic (tremolite-actinolite, albite, epidote, chlorite, magnetite), potassic (biotite, quartz, chlorite, K-feldspar, anhydrite) and sericitic (sericite, carbonate, quartz, chlorite, illite) alterations. Sodic-calcic alteration is more widespread in the region than >1 km2, reaches thicknesses of 500 m, and is occasionally overlain by potassic alterations, just like similar Fe-Oxide-Cu-Au (IOCG) deposits in the world. Tütün Tepeleri mineralizations are in the form of rare magnetite veins with intense magnetite dispersion within the sodic-calcic alteration developed in diorites. Mineral paragenesis is in the form of magnetite, molybdenite, pyrite, arsenopyrite, chalcopyrite, sphalerite, galena, hematite, malachite and azurite, and Ti content in magnetites is determined as 0.13–0.64%. Fe content is 20.13% on average. Formation temperatures in fluid inclusions measured in ore-bearing quartz veins are 320.3 °C on average and salinity is 11.32% NaCl equivalent on average. Isotope analysis results of these mineralizations show δ34Spyrite = 6–8.9; δ34Sc.pyrite = 3.8–5.5; δ18Oquartz was determined in the range of 10.8–13.2 and δD = (−37) – (−53). When the alteration types determined with isotope analysis results showing that the mineralization occurred in a magmatic-hydrothermal system, the low Ti content in the magnetites, the formation temperature and salinity values are evaluated together, it was anticipated that Tütün Tepeleri mineralization is an example of Fe-Oxide-Cu-Au (IOCG) deposits formed in a hydrothermal-magmatic system.
期刊介绍:
The Journal of African Earth Sciences sees itself as the prime geological journal for all aspects of the Earth Sciences about the African plate. Papers dealing with peripheral areas are welcome if they demonstrate a tight link with Africa.
The Journal publishes high quality, peer-reviewed scientific papers. It is devoted primarily to research papers but short communications relating to new developments of broad interest, reviews and book reviews will also be considered. Papers must have international appeal and should present work of more regional than local significance and dealing with well identified and justified scientific questions. Specialised technical papers, analytical or exploration reports must be avoided. Papers on applied geology should preferably be linked to such core disciplines and must be addressed to a more general geoscientific audience.